A Symmetry-Based Kinematic Theory for Nanocrystal Morphology Design

Cite This

Files in this item

Checksum: MD5:f3abb96c72ee27319ab0ad431fef5988

NI, Bing, Guillermo GONZÁLEZ-RUBIO, Felizitas KIRNER, Siyuan ZHANG, Helmut CÖLFEN, 2022. A Symmetry-Based Kinematic Theory for Nanocrystal Morphology Design. In: Angewandte Chemie International Edition. Wiley. 61(20), e202200753. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.202200753

@article{Ni2022-05-09Symme-56961, title={A Symmetry-Based Kinematic Theory for Nanocrystal Morphology Design}, year={2022}, doi={10.1002/anie.202200753}, number={20}, volume={61}, issn={1433-7851}, journal={Angewandte Chemie International Edition}, author={Ni, Bing and González-Rubio, Guillermo and Kirner, Felizitas and Zhang, Siyuan and Cölfen, Helmut}, note={Article Number: e202200753} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/56961"> <dc:creator>Kirner, Felizitas</dc:creator> <dc:contributor>Kirner, Felizitas</dc:contributor> <dcterms:title>A Symmetry-Based Kinematic Theory for Nanocrystal Morphology Design</dcterms:title> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2022-03-23T10:07:32Z</dc:date> <dc:creator>Ni, Bing</dc:creator> <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/56961"/> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/56961/1/Ni_2-13jpox65mjqwi2.pdf"/> <dc:creator>Zhang, Siyuan</dc:creator> <dc:contributor>Ni, Bing</dc:contributor> <dcterms:abstract xml:lang="eng">The growth of crystalline nanoparticles (NPs) generally involves three processes: nucleation, growth, and shape evolution. Among them, the shape evolution is less understood, despite the importance of morphology for NP properties. Here, we propose a symmetry-based kinematic theory (SBKT) based on classical growth theories to illustrate the process. Based on the crystal lattice, nucleus (or seed) symmetry, and the preferential growth directions under the experimental conditions, the SBKT can illustrate the growth trajectories. The theory accommodates the conventional criteria of the major existing theories for crystal growth and provides tools to better understand the symmetry-breaking process during the growth of anisotropic structures. Furthermore, complex dendritic growth is theoretically and experimentally demonstrated. Thus, it provides a framework to explain the shape evolution, and extends the morphogenesis prediction to cases, which cannot be treated by other theories.</dcterms:abstract> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2022-03-23T10:07:32Z</dcterms:available> <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by/4.0/"/> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:contributor>Cölfen, Helmut</dc:contributor> <dc:contributor>Zhang, Siyuan</dc:contributor> <dc:language>eng</dc:language> <dc:creator>Cölfen, Helmut</dc:creator> <dc:rights>Attribution 4.0 International</dc:rights> <dc:contributor>González-Rubio, Guillermo</dc:contributor> <dc:creator>González-Rubio, Guillermo</dc:creator> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/56961/1/Ni_2-13jpox65mjqwi2.pdf"/> <dcterms:issued>2022-05-09</dcterms:issued> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> </rdf:Description> </rdf:RDF>

Downloads since Mar 23, 2022 (Information about access statistics)

Ni_2-13jpox65mjqwi2.pdf 33

This item appears in the following Collection(s)

Attribution 4.0 International Except where otherwise noted, this item's license is described as Attribution 4.0 International

Search KOPS


Browse

My Account