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Type of Publication: | Journal article |
URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-87588 |
Author: | Ganteför, Gerd; Eberhardt, Wolfgang |
Year of publication: | 1996 |
Published in: | Physical Review Letters ; 76 (1996), 26. - pp. 4975-4978 |
DOI (citable link): | https://dx.doi.org/10.1103/PhysRevLett.76.4975 |
Summary: |
The photoelectron spectra of mass-selected negatively charged Nin- and Cun- clusters show similarities, which indicate an almost total localization of the Ni 3d orbitals corresponding to a maximum magnetic moment of 1μB per Ni atom. The similarity between Nin- and Cun- vanishes for n>7 corresponding to an increase in 3d delocalization. The data of Pdn- clusters suggest a Ni-like ( magnetic ) electronic structure for n = 3 6 and a Pt-like ( nonmagnetic ) one for n>15. There are indications that neutral Pd7 is a closed shell species (spin zero ground state).
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PACS Classification: | 36.40.Cg; 79.60.Bm; 75.50.Cc; 33.60.Cv |
Subject (DDC): | 530 Physics |
Link to License: | In Copyright |
GANTEFÖR, Gerd, Wolfgang EBERHARDT, 1996. Localization of 3 d and 4 d electrons in small clusters : the roots of magnetism. In: Physical Review Letters. 76(26), pp. 4975-4978. Available under: doi: 10.1103/PhysRevLett.76.4975
@article{Gantefor1996Local-5304, title={Localization of 3 d and 4 d electrons in small clusters : the roots of magnetism}, year={1996}, doi={10.1103/PhysRevLett.76.4975}, number={26}, volume={76}, journal={Physical Review Letters}, pages={4975--4978}, author={Ganteför, Gerd and Eberhardt, Wolfgang} }
PhysRevLett76199626.pdf | 327 |