Mode-Coupling Theory for Structural and Conformational Dynamics of Polymer Melts
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| Type of Publication: | Journal article |
| URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-37819 |
| Author: | Chong, Song-Ho; Fuchs, Matthias |
| Year of publication: | 2002 |
| Published in: | Physical Review Letters ; 88 (2002), 18. - 185702 |
| DOI (citable link): | https://dx.doi.org/10.1103/PhysRevLett.88.185702 |
| Summary: |
A mode-coupling theory for dense polymeric systems is developed which unifyingly incorporates the segmental cage effect relevant for structural slowing down and polymer chain conformational degrees of freedom. An ideal glass transition of polymer melts is predicted which becomes molecular-weight independent for large molecules. The theory provides a microscopic justification for the use of the Rouse theory in polymer melts, and the results for Rouse-mode correlators and mean-squared displacements are in good agreement with computer simulation results.
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| PACS Classification: | 61.25.Hq; 64.70.Pf; 61.20.Lc |
| Subject (DDC): | 530 Physics |
| Link to License: | Attribution-NonCommercial-NoDerivs 2.0 Generic |
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CHONG, Song-Ho, Matthias FUCHS, 2002. Mode-Coupling Theory for Structural and Conformational Dynamics of Polymer Melts. In: Physical Review Letters. 88(18), 185702. Available under: doi: 10.1103/PhysRevLett.88.185702
@article{Chong2002ModeC-5182, title={Mode-Coupling Theory for Structural and Conformational Dynamics of Polymer Melts}, year={2002}, doi={10.1103/PhysRevLett.88.185702}, number={18}, volume={88}, journal={Physical Review Letters}, author={Chong, Song-Ho and Fuchs, Matthias}, note={Article Number: 185702} }
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