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Synthesis of nickel hexacyanoferrate nanocubes with tuneable dimensions via temperature-controlled Ni<sup>2+</sup>-citrate complexation

Synthesis of nickel hexacyanoferrate nanocubes with tuneable dimensions via temperature-controlled Ni2+-citrate complexation

Type of Publication: Journal article
Publication status: Published
Author: Keßler, Sascha; González-Rubio, Guillermo; Reinalter, Elrike Rea; Kovermann, Michael; Cölfen, Helmut
Year of publication: 2020
Published in: Chemical Communications ; 56 (2020), 92. - pp. 14439-14442. - Royal Society of Chemistry (RSC). - ISSN 0009-241X. - eISSN 1364-548X
Pubmed ID: 33146182
DOI (citable link): https://dx.doi.org/10.1039/D0CC04628K
Summary:
The citrate-assisted growth of nickel hexacyanoferrate (NiHCF) nanocubes was investigated. Control over the complexation of Ni2+ ions with citrate at different temperatures enabled fine tuning of the nanocrystal (NC) dimensions and their self-assembly into mesocrystals. Our results introduce new concepts towards the synthesis of NiHCF NCs, potentially applicable to other members of the Prussian blue analogues family.
Subject (DDC): 540 Chemistry
Bibliography of Konstanz: Yes
Refereed: Yes

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KESSLER, Sascha, Guillermo GONZÁLEZ-RUBIO, Elrike Rea REINALTER, Michael KOVERMANN, Helmut CÖLFEN, 2020. Synthesis of nickel hexacyanoferrate nanocubes with tuneable dimensions via temperature-controlled Ni2+-citrate complexation. In: Chemical Communications. Royal Society of Chemistry (RSC). 56(92), pp. 14439-14442. ISSN 0009-241X. eISSN 1364-548X. Available under: doi: 10.1039/D0CC04628K

@article{Keler2020-11-19Synth-51768, title={Synthesis of nickel hexacyanoferrate nanocubes with tuneable dimensions via temperature-controlled Ni2+-citrate complexation}, year={2020}, doi={10.1039/D0CC04628K}, number={92}, volume={56}, issn={0009-241X}, journal={Chemical Communications}, pages={14439--14442}, author={Keßler, Sascha and González-Rubio, Guillermo and Reinalter, Elrike Rea and Kovermann, Michael and Cölfen, Helmut} }

Reinalter, Elrike Rea Kovermann, Michael Cölfen, Helmut González-Rubio, Guillermo González-Rubio, Guillermo 2020-11-13T10:22:56Z 2020-11-19 terms-of-use Reinalter, Elrike Rea 2020-11-13T10:22:56Z Cölfen, Helmut Keßler, Sascha eng Kovermann, Michael The citrate-assisted growth of nickel hexacyanoferrate (NiHCF) nanocubes was investigated. Control over the complexation of Ni<sup>2+</sup> ions with citrate at different temperatures enabled fine tuning of the nanocrystal (NC) dimensions and their self-assembly into mesocrystals. Our results introduce new concepts towards the synthesis of NiHCF NCs, potentially applicable to other members of the Prussian blue analogues family. Synthesis of nickel hexacyanoferrate nanocubes with tuneable dimensions via temperature-controlled Ni<sup>2+</sup>-citrate complexation Keßler, Sascha

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