KOPS - Das Institutionelle Repositorium der Universität Konstanz

Single-molecule magnets : a new approach to investigate the electronic structure of Mn12 molecules by scanning tunneling spectroscopy

Single-molecule magnets : a new approach to investigate the electronic structure of Mn12 molecules by scanning tunneling spectroscopy

Zitieren

Dateien zu dieser Ressource

Prüfsumme: MD5:712d608bedfe08c975d666eb93835e74

BURGERT, Michael, Sönke VOSS, Simon HERR, Mikhail FONIN, Ulrich GROTH, Ulrich RÜDIGER, 2007. Single-molecule magnets : a new approach to investigate the electronic structure of Mn12 molecules by scanning tunneling spectroscopy. In: Journal of the American Chemical Society. 129(46), pp. 14362-14366

@article{Burgert2007Singl-5170, title={Single-molecule magnets : a new approach to investigate the electronic structure of Mn12 molecules by scanning tunneling spectroscopy}, year={2007}, doi={10.1021/ja074884z}, number={46}, volume={129}, journal={Journal of the American Chemical Society}, pages={14362--14366}, author={Burgert, Michael and Voss, Sönke and Herr, Simon and Fonin, Mikhail and Groth, Ulrich and Rüdiger, Ulrich} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/5170"> <dc:creator>Burgert, Michael</dc:creator> <dc:contributor>Voss, Sönke</dc:contributor> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/5170"/> <dcterms:issued>2007</dcterms:issued> <dc:contributor>Fonin, Mikhail</dc:contributor> <dcterms:title>Single-molecule magnets : a new approach to investigate the electronic structure of Mn12 molecules by scanning tunneling spectroscopy</dcterms:title> <dc:creator>Voss, Sönke</dc:creator> <dcterms:bibliographicCitation>First publ. in: Journal of the American Chemical Society ; 129 (2007), 46. - S. 14362-14366</dcterms:bibliographicCitation> <dc:creator>Herr, Simon</dc:creator> <dc:contributor>Herr, Simon</dc:contributor> <dc:creator>Fonin, Mikhail</dc:creator> <dcterms:abstract xml:lang="eng">A new approach to the deposition of Mn12 single-molecule magnet monolayers on the functionalized Au(111) surface optimized for the investigation by means of scanning tunneling spectroscopy was developed. To demonstrate this method, the new Mn12 complex [Mn12O12(O2CC6H4F)16(EtOH)4]·4.4CHCl3 was synthesized and characterized. In MALDI-TOF mass spectra the isotopic distribution of the molecular ion peak of the latter complex was revealed. The complex was grafted to Au(111) surfaces via two different short conducting linker molecules. The Mn12 molecules deposited on the functionalized surface were characterized by means of scanning tunneling microscopy showing homogeneous monolayers of highest quality. Scanning tunneling spectroscopy measurements over a wider energy range compared with previous results could be performed because of the optimized Au(111) surface functionalization. Furthermore, the results substantiate the general suitability of short acidic linker molecules for the preparation of Mn12 monolayers via ligand exchange and represent a crucial step toward addressing the magnetic properties of individual Mn12 single-molecule magnets.</dcterms:abstract> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:53:43Z</dc:date> <dc:format>application/pdf</dc:format> <dc:contributor>Rüdiger, Ulrich</dc:contributor> <dc:rights>deposit-license</dc:rights> <dc:language>eng</dc:language> <dc:creator>Rüdiger, Ulrich</dc:creator> <dc:contributor>Groth, Ulrich</dc:contributor> <dc:contributor>Burgert, Michael</dc:contributor> <dc:creator>Groth, Ulrich</dc:creator> </rdf:Description> </rdf:RDF>

Dateiabrufe seit 01.10.2014 (Informationen über die Zugriffsstatistik)

Single_molecule_magnets.pdf 153

Das Dokument erscheint in:

deposit-license Solange nicht anders angezeigt, wird die Lizenz wie folgt beschrieben: deposit-license

KOPS Suche


Stöbern

Mein Benutzerkonto