Aufgrund von Vorbereitungen auf eine neue Version von KOPS, können kommenden Montag und Dienstag keine Publikationen eingereicht werden. (Due to preparations for a new version of KOPS, no publications can be submitted next Monday and Tuesday.)
Type of Publication: | Journal article |
URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-88160 |
Author: | Cha, Chia-Yen; Ganteför, Gerd; Eberhardt, Wolfgang |
Year of publication: | 1993 |
Published in: | Journal of Chemical Physics ; 99 (1993), 9. - pp. 6308-6312 |
DOI (citable link): | https://dx.doi.org/10.1063/1.465868 |
Summary: |
We present a comparison of the electronic level structure of Cu - n clusters with the jellium model using photoelectron spectroscopy of metal cluster anions. The spectra are recorded at an energy resolution of 30 meV using photon energies of up to 6.4 eV. We obtain a well resolved picture of the electronic structure of the 4s derived electronic states in the energy region between the localized 3d derived states and the highest occupied molecular orbital. The observed features can be assigned to the 1s, 1p, and 1d shells predicted by the jellium model if ellipsoidal distortions and effects like shake-up processes, multiplet splittings and the s–d hybridization are taken into consideration.
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PACS Classification: | 33.60.-q; 36.40.+d |
Subject (DDC): | 530 Physics |
Keywords: | Photoelectron spectroscopy, Copper ions, Ion Pairs, Correlations, Jellium model, Electronic structure, Energy resolution, Localized states |
Link to License: | In Copyright |
CHA, Chia-Yen, Gerd GANTEFÖR, Wolfgang EBERHARDT, 1993. Photoelectron spectroscopy of Cun- clusters : comparison with jellium model predictions. In: Journal of Chemical Physics. 99(9), pp. 6308-6312. Available under: doi: 10.1063/1.465868
@article{Cha1993Photo-5122, title={Photoelectron spectroscopy of Cun- clusters : comparison with jellium model predictions}, year={1993}, doi={10.1063/1.465868}, number={9}, volume={99}, journal={Journal of Chemical Physics}, pages={6308--6312}, author={Cha, Chia-Yen and Ganteför, Gerd and Eberhardt, Wolfgang} }
JChemPhys991993.pdf | 491 |