Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry

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Chemistry - A European Journal ; 26 (2020), 72. - pp. 17546-17558. - Wiley. - ISSN 0947-6539. - eISSN 1521-3765
Abstract
Cross coupling products of bowl-shaped as -indaceno[3,2,1,8,7,6- pqrstuv ]picene (Idpc) and different planar arenes and ethynyl-arenes were synthesized by either Suzuki or Sonogashira cross coupling. Photoluminescence as well as electrochemical properties of all products were investigated and complemented by time-dependent quantum chemical calculations. UV/vis- spectroelectrochemistry investigations of the directly linked (Idpc) 2 ( 9 ) uncovered the formation of 65 % (Idpc) 2 •- as the major reduction product. All coupling products showed fluorescence. Ferrocene-1-yl-Idpc was structurally characterized by X-ray diffraction and is a rare example of a ferrocene-containing buckybowl exhibiting luminescence.
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ISO 690BAYER, Johannes, Jan HERBERGER, Lukas HOLZ, Rainer F. WINTER, Thomas HUHN, 2020. Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry. In: Chemistry - A European Journal. Wiley. 26(72), pp. 17546-17558. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.202003605
BibTex
@article{Bayer2020-12-23Geode-50710,
  year={2020},
  doi={10.1002/chem.202003605},
  title={Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry},
  number={72},
  volume={26},
  issn={0947-6539},
  journal={Chemistry - A European Journal},
  pages={17546--17558},
  author={Bayer, Johannes and Herberger, Jan and Holz, Lukas and Winter, Rainer F. and Huhn, Thomas}
}
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