Aufgrund von Vorbereitungen auf eine neue Version von KOPS, können kommenden Montag und Dienstag keine Publikationen eingereicht werden. (Due to preparations for a new version of KOPS, no publications can be submitted next Monday and Tuesday.)
Type of Publication: | Journal article |
Publication status: | Published |
URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-2-diz3kpuyltkl8 |
Author: | Bayer, Johannes; Herberger, Jan; Holz, Lukas; Winter, Rainer; Huhn, Thomas |
Year of publication: | 2020 |
Published in: | Chemistry - A European Journal ; 26 (2020), 72. - pp. 17546-17558. - Wiley. - ISSN 0947-6539. - eISSN 1521-3765 |
Pubmed ID: | 32846003 |
DOI (citable link): | https://dx.doi.org/10.1002/chem.202003605 |
Summary: |
Cross coupling products of bowl-shaped as -indaceno[3,2,1,8,7,6- pqrstuv ]picene (Idpc) and different planar arenes and ethynyl-arenes were synthesized by either Suzuki or Sonogashira cross coupling. Photoluminescence as well as electrochemical properties of all products were investigated and complemented by time-dependent quantum chemical calculations. UV/vis- spectroelectrochemistry investigations of the directly linked (Idpc) 2 ( 9 ) uncovered the formation of 65 % (Idpc) 2 •- as the major reduction product. All coupling products showed fluorescence. Ferrocene-1-yl-Idpc was structurally characterized by X-ray diffraction and is a rare example of a ferrocene-containing buckybowl exhibiting luminescence.
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Subject (DDC): | 540 Chemistry |
Link to License: | Attribution-NonCommercial-NoDerivatives 4.0 International |
Bibliography of Konstanz: | Yes |
Refereed: | Yes |
BAYER, Johannes, Jan HERBERGER, Lukas HOLZ, Rainer WINTER, Thomas HUHN, 2020. Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry. In: Chemistry - A European Journal. Wiley. 26(72), pp. 17546-17558. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.202003605
@article{Bayer2020-12-23Geode-50710, title={Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry}, year={2020}, doi={10.1002/chem.202003605}, number={72}, volume={26}, issn={0947-6539}, journal={Chemistry - A European Journal}, pages={17546--17558}, author={Bayer, Johannes and Herberger, Jan and Holz, Lukas and Winter, Rainer and Huhn, Thomas} }
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