Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry
| Type of Publication: | Journal article |
| Publication status: | Published |
| URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-2-diz3kpuyltkl8 |
| Author: | Bayer, Johannes; Herberger, Jan; Holz, Lukas; Winter, Rainer; Huhn, Thomas |
| Year of publication: | 2020 |
| Published in: | Chemistry - A European Journal ; 26 (2020), 72. - pp. 17546-17558. - Wiley. - ISSN 0947-6539. - eISSN 1521-3765 |
| Pubmed ID: | 32846003 |
| DOI (citable link): | https://dx.doi.org/10.1002/chem.202003605 |
| Summary: |
Cross coupling products of bowl-shaped as -indaceno[3,2,1,8,7,6- pqrstuv ]picene (Idpc) and different planar arenes and ethynyl-arenes were synthesized by either Suzuki or Sonogashira cross coupling. Photoluminescence as well as electrochemical properties of all products were investigated and complemented by time-dependent quantum chemical calculations. UV/vis- spectroelectrochemistry investigations of the directly linked (Idpc) 2 ( 9 ) uncovered the formation of 65 % (Idpc) 2 •- as the major reduction product. All coupling products showed fluorescence. Ferrocene-1-yl-Idpc was structurally characterized by X-ray diffraction and is a rare example of a ferrocene-containing buckybowl exhibiting luminescence.
|
| Subject (DDC): | 540 Chemistry |
| Link to License: | In Copyright |
| Bibliography of Konstanz: | Yes |
| Refereed: | Yes |
Cite This
Files in this item
![[PDF]](/themes/Kops/images/mimes/pdf.png "PDF file"){kind=small}
BAYER, Johannes, Jan HERBERGER, Lukas HOLZ, Rainer WINTER, Thomas HUHN, 2020. Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry. In: Chemistry - A European Journal. Wiley. 26(72), pp. 17546-17558. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.202003605
@article{Bayer2020-12-23Geode-50710, title={Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry}, year={2020}, doi={10.1002/chem.202003605}, number={72}, volume={26}, issn={0947-6539}, journal={Chemistry - A European Journal}, pages={17546--17558}, author={Bayer, Johannes and Herberger, Jan and Holz, Lukas and Winter, Rainer and Huhn, Thomas} }
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/50710"> <dc:creator>Holz, Lukas</dc:creator> <dc:contributor>Holz, Lukas</dc:contributor> <dc:creator>Huhn, Thomas</dc:creator> <dc:language>eng</dc:language> <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/> <dc:creator>Winter, Rainer</dc:creator> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2020-09-07T14:55:10Z</dc:date> <dc:contributor>Bayer, Johannes</dc:contributor> <dc:contributor>Huhn, Thomas</dc:contributor> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dcterms:abstract xml:lang="eng">Cross coupling products of bowl-shaped as -indaceno[3,2,1,8,7,6- pqrstuv ]picene (Idpc) and different planar arenes and ethynyl-arenes were synthesized by either Suzuki or Sonogashira cross coupling. Photoluminescence as well as electrochemical properties of all products were investigated and complemented by time-dependent quantum chemical calculations. UV/vis- spectroelectrochemistry investigations of the directly linked (Idpc) 2 ( 9 ) uncovered the formation of 65 % (Idpc) 2 •- as the major reduction product. All coupling products showed fluorescence. Ferrocene-1-yl-Idpc was structurally characterized by X-ray diffraction and is a rare example of a ferrocene-containing buckybowl exhibiting luminescence.</dcterms:abstract> <dc:contributor>Herberger, Jan</dc:contributor> <dcterms:issued>2020-12-23</dcterms:issued> <dc:rights>terms-of-use</dc:rights> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2020-09-07T14:55:10Z</dcterms:available> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/50710/1/Bayer_2-diz3kpuyltkl8.pdf"/> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/50710/1/Bayer_2-diz3kpuyltkl8.pdf"/> <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/50710"/> <dcterms:title>Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry</dcterms:title> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:creator>Bayer, Johannes</dc:creator> <dc:creator>Herberger, Jan</dc:creator> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:contributor>Winter, Rainer</dc:contributor> </rdf:Description> </rdf:RDF>
Downloads since Sep 7, 2020 (Information about access statistics)
| Bayer_2-diz3kpuyltkl8.pdf | 105 |
This item appears in the following Collection(s)
Search KOPS
Browse
My Account
