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N-Heterocyclic Carbene Palladium Catalyzed Regioselective Oxidative Trifluoroacetoxylation of Unactivated Methylene sp<sup>3</sup> C–H Bonds in Linear Alkyl Esters

N-Heterocyclic Carbene Palladium Catalyzed Regioselective Oxidative Trifluoroacetoxylation of Unactivated Methylene sp3 C–H Bonds in Linear Alkyl Esters

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HOU, Xiu-Feng, Ya-Nong WANG, Inigo GÖTTKER-SCHNETMANN, 2011. N-Heterocyclic Carbene Palladium Catalyzed Regioselective Oxidative Trifluoroacetoxylation of Unactivated Methylene sp3 C–H Bonds in Linear Alkyl Esters. In: Organometallics. American Chemical Society (ACS). 30(21), pp. 6053-6056. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om200484g

@article{Hou2011-11-14NHete-50657, title={N-Heterocyclic Carbene Palladium Catalyzed Regioselective Oxidative Trifluoroacetoxylation of Unactivated Methylene sp3 C–H Bonds in Linear Alkyl Esters}, year={2011}, doi={10.1021/om200484g}, number={21}, volume={30}, issn={0276-7333}, journal={Organometallics}, pages={6053--6056}, author={Hou, Xiu-Feng and Wang, Ya-Nong and Göttker-Schnetmann, Inigo} }

N-Heterocyclic Carbene Palladium Catalyzed Regioselective Oxidative Trifluoroacetoxylation of Unactivated Methylene sp<sup>3</sup> C–H Bonds in Linear Alkyl Esters Hou, Xiu-Feng 2011-11-14 Several N-heterocyclic carbene palladium catalyzed oxidation of nonactivated sp<sup>3</sup> C–H bonds in linear primary and secondary trifluoroacetic acid esters have been developed. A high selectivity for the oxidation of the omega-1 carbon atom in trifluoroacetic acid n-propyl to n-octyl esters was realized by an appropriate choice of N-heterocyclic carbene palladium complexes. 2020-09-02T09:22:03Z eng Wang, Ya-Nong Hou, Xiu-Feng Wang, Ya-Nong Göttker-Schnetmann, Inigo 2020-09-02T09:22:03Z Göttker-Schnetmann, Inigo

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