Polymer-Mode-Coupling Theory of Finite-Size-Fluctuation Effects in Entangled Solutions, Melts, and Gels. 1. General Formulation and Predictions
Polymer-Mode-Coupling Theory of Finite-Size-Fluctuation Effects in Entangled Solutions, Melts, and Gels. 1. General Formulation and Predictions
Date
1997
Authors
Schweizer, Kenneth S.
Editors
Journal ISSN
Electronic ISSN
ISBN
Bibliographical data
Publisher
Series
URI (citable link)
DOI (citable link)
International patent number
Link to the license
EU project number
Project
Open Access publication
Collections
Title in another language
Publication type
Journal article
Publication status
Published in
Macromolecules ; 30 (1997). - pp. 5133-5155
Abstract
The transport coefficients of dense polymeric fluids are approximately calculated from the microscopic intermolecular forces. The following finite molecular weight effects are discussed within the polymer-mode-coupling theory (PMC) and compared to the corresponding reptation/tube ideas: constraint release mechanism, spatial inhomogeneity of the entanglement constraints, and tracer polymer shape fluctuations. The entanglement corrections to the single polymer Rouse dynamics are shown to depend on molecular weight via the ratio N/Ne, where the entanglement degree of polymerization, Ne, can be measured from the plateau shear modulus.
Summary in another language
Subject (DDC)
530 Physics
Keywords
Conference
Review
undefined / . - undefined, undefined. - (undefined; undefined)
Cite This
ISO 690
FUCHS, Matthias, Kenneth S. SCHWEIZER, 1997. Polymer-Mode-Coupling Theory of Finite-Size-Fluctuation Effects in Entangled Solutions, Melts, and Gels. 1. General Formulation and Predictions. In: Macromolecules. 30, pp. 5133-5155. Available under: doi: 10.1021/ma970234bBibTex
@article{Fuchs1997Polym-4936, year={1997}, doi={10.1021/ma970234b}, title={Polymer-Mode-Coupling Theory of Finite-Size-Fluctuation Effects in Entangled Solutions, Melts, and Gels. 1. General Formulation and Predictions}, volume={30}, journal={Macromolecules}, pages={5133--5155}, author={Fuchs, Matthias and Schweizer, Kenneth S.} }
RDF
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/4936"> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:51:30Z</dcterms:available> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4936/1/ploymer_mode_coupling_theory_of.pdf"/> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/4936"/> <dc:contributor>Schweizer, Kenneth S.</dc:contributor> <dc:format>application/pdf</dc:format> <dc:contributor>Fuchs, Matthias</dc:contributor> <dc:creator>Schweizer, Kenneth S.</dc:creator> <dcterms:issued>1997</dcterms:issued> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/> <dcterms:abstract xml:lang="eng">The transport coefficients of dense polymeric fluids are approximately calculated from the microscopic intermolecular forces. The following finite molecular weight effects are discussed within the polymer-mode-coupling theory (PMC) and compared to the corresponding reptation/tube ideas: constraint release mechanism, spatial inhomogeneity of the entanglement constraints, and tracer polymer shape fluctuations. The entanglement corrections to the single polymer Rouse dynamics are shown to depend on molecular weight via the ratio N/Ne, where the entanglement degree of polymerization, Ne, can be measured from the plateau shear modulus.</dcterms:abstract> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by-nc-nd/2.0/"/> <dc:language>eng</dc:language> <foaf:homepage rdf:resource="http://localhost:8080/"/> <dcterms:title>Polymer-Mode-Coupling Theory of Finite-Size-Fluctuation Effects in Entangled Solutions, Melts, and Gels. 1. General Formulation and Predictions</dcterms:title> <dc:creator>Fuchs, Matthias</dc:creator> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:51:30Z</dc:date> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4936/1/ploymer_mode_coupling_theory_of.pdf"/> <dc:rights>Attribution-NonCommercial-NoDerivs 2.0 Generic</dc:rights> <dcterms:bibliographicCitation>First publ. in: Macromolecules 30 (1997), pp. 5133-5155</dcterms:bibliographicCitation> </rdf:Description> </rdf:RDF>
Internal note
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Examination date of dissertation
Method of financing
Comment on publication
Alliance license
Corresponding Authors der Uni Konstanz vorhanden
International Co-Authors
Bibliography of Konstanz
No