AlH3 and Al2H6 : magic clusters with unmagical properties

Zitieren

Dateien zu dieser Ressource

Prüfsumme: MD5:bde6216600c70c3cf4e704bcd0662ec1

RAO, Bijan K., Purusottam JENA, Stefan BURKART, Gerd GANTEFÖR, Gotthard SEIFERT, 2001. AlH3 and Al2H6 : magic clusters with unmagical properties. In: Physical Review Letters. 86(4), pp. 692-695. Available under: doi: 10.17877/DE290R-12122

@article{Rao2001Al2H6-4771, title={AlH3 and Al2H6 : magic clusters with unmagical properties}, year={2001}, doi={10.17877/DE290R-12122}, number={4}, volume={86}, journal={Physical Review Letters}, pages={692--695}, author={Rao, Bijan K. and Jena, Purusottam and Burkart, Stefan and Ganteför, Gerd and Seifert, Gotthard} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/4771"> <dc:contributor>Rao, Bijan K.</dc:contributor> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4771/1/PhysRevLett862001.pdf"/> <dcterms:abstract xml:lang="eng">Enhanced stability, low electron affinity, and high ionization potential are the hallmarks of a magic cluster. With an electron affinity of 0.28 eV, ionization potential of 11.43 eV, and a large binding energy, AlH3 satisfies these criteria. However, unlike other magic clusters that interact only weakly with each other, two AlH3 clusters bind to each other with an energy of 1.54 eV. The resulting Al2H6, while also a magic cluster in its own right, possesses the most unusual property that the difference between its adiabatic and vertical detachment energy is about 2 eV the largest of any known cluster. These results, based on density functional theory, are verified experimentally through photodetachment spectroscopy.</dcterms:abstract> <dc:creator>Rao, Bijan K.</dc:creator> <dc:contributor>Seifert, Gotthard</dc:contributor> <dc:contributor>Ganteför, Gerd</dc:contributor> <dc:contributor>Jena, Purusottam</dc:contributor> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/41"/> <dcterms:bibliographicCitation>First publ. in: Physical Review Letters 86 (2001), 4, pp. 692 - 695</dcterms:bibliographicCitation> <dcterms:issued>2001</dcterms:issued> <dc:creator>Burkart, Stefan</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:50:13Z</dcterms:available> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103416863-3868037-7"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:50:13Z</dc:date> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:contributor>Burkart, Stefan</dc:contributor> <dc:creator>Jena, Purusottam</dc:creator> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dc:creator>Ganteför, Gerd</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/4771"/> <dc:language>eng</dc:language> <dc:creator>Seifert, Gotthard</dc:creator> <dc:format>application/pdf</dc:format> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4771/1/PhysRevLett862001.pdf"/> <dc:rights>deposit-license</dc:rights> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/41"/> <dcterms:title>AlH3 and Al2H6 : magic clusters with unmagical properties</dcterms:title> </rdf:Description> </rdf:RDF>

Dateiabrufe seit 01.10.2014 (Informationen über die Zugriffsstatistik)

PhysRevLett862001.pdf 392

Das Dokument erscheint in:

KOPS Suche


Stöbern

Mein Benutzerkonto