KOPS - The Institutional Repository of the University of Konstanz

Effect of Charge Assisted Hydrogen Bonds on Single Molecule Electron Transport

Effect of Charge Assisted Hydrogen Bonds on Single Molecule Electron Transport

Cite This

Files in this item

Files Size Format View

There are no files associated with this item.

SACCHETTI, Valentina, Javier RAMOS-SORIANO, Beatriz M. ILLESCAS, M. Teresa GONZÁLEZ, Dongzhe LI, Lucía PALOMINO-RUIZ, Irene R. MARQUEZ, Edmund LEARY, Gabino RUBIO-BOLLINGER, Fabian PAULY, Nicolás AGRAÏT, Nazario MARTÍN, 2019. Effect of Charge Assisted Hydrogen Bonds on Single Molecule Electron Transport. In: The Journal of Physical Chemistry C. 123(48), pp. 29386-29393. ISSN 1932-7447. eISSN 1932-7455. Available under: doi: 10.1021/acs.jpcc.9b06850

@article{Sacchetti2019-12-05Effec-47484, title={Effect of Charge Assisted Hydrogen Bonds on Single Molecule Electron Transport}, year={2019}, doi={10.1021/acs.jpcc.9b06850}, number={48}, volume={123}, issn={1932-7447}, journal={The Journal of Physical Chemistry C}, pages={29386--29393}, author={Sacchetti, Valentina and Ramos-Soriano, Javier and Illescas, Beatriz M. and González, M. Teresa and Li, Dongzhe and Palomino-Ruiz, Lucía and Marquez, Irene R. and Leary, Edmund and Rubio-Bollinger, Gabino and Pauly, Fabian and Agraït, Nicolás and Martín, Nazario} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/47484"> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2019-11-13T13:53:49Z</dc:date> <dc:creator>Palomino-Ruiz, Lucía</dc:creator> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:contributor>Illescas, Beatriz M.</dc:contributor> <dc:contributor>Marquez, Irene R.</dc:contributor> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dcterms:abstract xml:lang="eng">The effect of the in-bone presence of charge assisted hydro-gen bonds in the conductance of single-molecule junctions has been studied by the scanning-tunneling microscope break-junction (STMBJ) technique. In particular two amidinium-carboxylate supramolecular complexes of differ-ent length have been tested. We observed that the ionic character that gives extra stability to the charge assisted hydrogen bond is however hindering the electron transport through the complexes. Theoretical calculations using the DFT+ method indicate that both the HOMO and LUMO of the complexes are fully localized in only one of the moieties of the complex explaining the low single molecular conductance of the compounds.</dcterms:abstract> <dc:creator>Leary, Edmund</dc:creator> <dc:contributor>Rubio-Bollinger, Gabino</dc:contributor> <dc:creator>Rubio-Bollinger, Gabino</dc:creator> <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/47484"/> <dc:contributor>Ramos-Soriano, Javier</dc:contributor> <dc:contributor>Palomino-Ruiz, Lucía</dc:contributor> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/41"/> <dcterms:title>Effect of Charge Assisted Hydrogen Bonds on Single Molecule Electron Transport</dcterms:title> <dc:contributor>González, M. Teresa</dc:contributor> <dc:creator>Illescas, Beatriz M.</dc:creator> <dc:creator>González, M. Teresa</dc:creator> <dc:contributor>Martín, Nazario</dc:contributor> <dc:creator>Marquez, Irene R.</dc:creator> <dc:creator>Martín, Nazario</dc:creator> <dc:creator>Agraït, Nicolás</dc:creator> <dc:contributor>Pauly, Fabian</dc:contributor> <dc:contributor>Leary, Edmund</dc:contributor> <dc:creator>Ramos-Soriano, Javier</dc:creator> <dc:language>eng</dc:language> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2019-11-13T13:53:49Z</dcterms:available> <dcterms:issued>2019-12-05</dcterms:issued> <dc:contributor>Li, Dongzhe</dc:contributor> <dc:contributor>Sacchetti, Valentina</dc:contributor> <dc:creator>Li, Dongzhe</dc:creator> <dc:creator>Pauly, Fabian</dc:creator> <dc:creator>Sacchetti, Valentina</dc:creator> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/41"/> <dc:contributor>Agraït, Nicolás</dc:contributor> </rdf:Description> </rdf:RDF>

This item appears in the following Collection(s)

Search KOPS


Browse

My Account