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Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

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MAGNABOSCO, Giulia, Andrea M. M. CONDORELLI, Rose ROSENBERG, Iryna POLISHCHUK, Boaz POKROY, Denis GEBAUER, Helmut CÖLFEN, Giuseppe FALINI, 2019. Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol. In: Chemical Communications. 55(86), pp. 12944-12947. ISSN 0009-241X. eISSN 1364-548X. Available under: doi: 10.1039/C9CC07087G

@article{Magnabosco2019-10-24Nonst-47193, title={Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol}, year={2019}, doi={10.1039/C9CC07087G}, number={86}, volume={55}, issn={0009-241X}, journal={Chemical Communications}, pages={12944--12947}, author={Magnabosco, Giulia and Condorelli, Andrea M. M. and Rosenberg, Rose and Polishchuk, Iryna and Pokroy, Boaz and Gebauer, Denis and Cölfen, Helmut and Falini, Giuseppe} }

Cölfen, Helmut Cölfen, Helmut eng Falini, Giuseppe 2019-10-11T09:20:35Z Polishchuk, Iryna Gebauer, Denis Condorelli, Andrea M. M. Gebauer, Denis Rosenberg, Rose Polishchuk, Iryna Condorelli, Andrea M. M. Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol 2019-10-24 Magnabosco, Giulia Rosenberg, Rose Falini, Giuseppe 2019-10-11T09:20:35Z Pokroy, Boaz Magnabosco, Giulia The effect of Mg<sup>2+</sup> on the precipitation pathway of CaCO<sub>3</sub> in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg<sup>2+</sup> promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate. Pokroy, Boaz

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