New Horizons of Non-Classical Crystallization

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Journal of the American Chemical Society. 2019, 141(26), pp. 10120-10136. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.9b01883
Zusammenfassung

Non-Classical Crystallization (NCC) summarizes a number of crystallization pathways, which differ from the classical lay-er-by-layer growth of crystals involving atomic/molecular building units. Common to NCC is that the building units are larger and include nanoparticles, clusters or liquid droplets, providing multiple handles for their control at each elementary step. Therefore, many different pathways towards the final single crystals are possible and can be influenced by appropriate experimental parameters or additives at each step of crystal formation and growth. As a consequence, NCC allows for a plethora of crystallization strategies towards complex crystalline (hybrid)materials. In this perspective, we summarize the current state of the art with a focus on the new horizons for NCC with respect to mechanistic understanding, high-performance materials and new applications. This gives a glimpse on what will be possible in the future using these crystallization approaches: Examples are new electrode and storage materials, (photo)catalysts, building materials, porous or crystalline materials with complex shape, structural hierarchy and anisotropic single crystals.

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ISO 690JEHANNIN, Marie, Ashit RAO, Helmut CÖLFEN, 2019. New Horizons of Non-Classical Crystallization. In: Journal of the American Chemical Society. 2019, 141(26), pp. 10120-10136. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.9b01883
BibTex
@article{Jehannin2019-07-03Horiz-46019,
  year={2019},
  doi={10.1021/jacs.9b01883},
  title={New Horizons of Non-Classical Crystallization},
  number={26},
  volume={141},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={10120--10136},
  author={Jehannin, Marie and Rao, Ashit and Cölfen, Helmut}
}
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