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Metallo‐Scorpionates : First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)

Metallo‐Scorpionates : First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)

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SCHLAPP-HACKL, Inge, Christopher HASSENRÜCK, Klaus WURST, Holger KOPACKA, Thomas MÜLLER, Rainer F. WINTER, Benno BILDSTEIN, 2018. Metallo‐Scorpionates : First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu). In: European Journal of Inorganic Chemistry. 2018(40), pp. 4434-4441. ISSN 1434-1948. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201800774

@article{SchlappHackl2018-11-01Metal-44250, title={Metallo‐Scorpionates : First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)}, year={2018}, doi={10.1002/ejic.201800774}, number={40}, volume={2018}, issn={1434-1948}, journal={European Journal of Inorganic Chemistry}, pages={4434--4441}, author={Schlapp-Hackl, Inge and Hassenrück, Christopher and Wurst, Klaus and Kopacka, Holger and Müller, Thomas and Winter, Rainer F. and Bildstein, Benno} }

Wurst, Klaus 2018-11-01 Metallo‐Scorpionates : First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu) Bildstein, Benno eng 2018-12-10T14:45:20Z The first metallo‐scorpionate ligands, closely related to Trofimenko's scorpionates, are obtained by formal replacement of the hydrido‐boron moiety of hydrido‐tris(pyrazolyl)borate by an (arene)Ru<sup>II</sup> fragment. Coordination to divalent and trivalent 3d‐transition metals (Fe, Co, Ni, Cu) gives access to a series of homoleptic, heterotrimetallic complexes containing linear metal chains bridged by pyrazole ligands. Synthetic aspects, spectroscopic, structural and electrochemical properties are reported and compared to those of standard scorpionate complexes. Winter, Rainer F. Wurst, Klaus 2018-12-10T14:45:20Z terms-of-use Bildstein, Benno Winter, Rainer F. Müller, Thomas Hassenrück, Christopher Müller, Thomas Schlapp-Hackl, Inge Kopacka, Holger Schlapp-Hackl, Inge Kopacka, Holger Hassenrück, Christopher

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