Microalgae lipids as a feedstock for the production of benzene

Pingen, Dennis; Zimmerer, Julia; Klinkenberg, Nele; Mecking, Stefan

Microalgae lipids as a feedstock for the production of benzene

Dateien

Pingen_2-pvan9egn5g9n9.pdfGröße: 143.81 KBDownloads: 397

Datum

2018

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie
Zukunftskolleg

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Green Chemistry. 2018, 20(8), pp. 1874-1878. ISSN 1463-9262. eISSN 1463-9270. Available under: doi: 10.1039/c8gc00423d

Zusammenfassung

A two-step one-pot synthesis of benzene from the five-fold unsaturated fatty acid eicosapentaenoic acid (EPA), a component of microalgae oils, is presented. By a sequence of olefin metathesis and the catalytic dehydrogenation of the resulting 1,4-cyclohexadiene, two equivalents of benzene are effectively formed per EPA substrate molecule. As the only major by-products, 5-octenoic acid and 5-decenedioic acid are formed. Performing the dehydrogenation step under hydrogen pressure results in the formation of their saturated analogues, sebacic acid and octanoic acid, both desirable products, while the simultaneous dehydrogenation step to benzene is not hampered.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

PINGEN, Dennis, Julia ZIMMERER, Nele KLINKENBERG, Stefan MECKING, 2018. Microalgae lipids as a feedstock for the production of benzene. In: Green Chemistry. 2018, 20(8), pp. 1874-1878. ISSN 1463-9262. eISSN 1463-9270. Available under: doi: 10.1039/c8gc00423d

BibTex

@article{Pingen2018Micro-42418,
  year={2018},
  doi={10.1039/c8gc00423d},
  title={Microalgae lipids as a feedstock for the production of benzene},
  number={8},
  volume={20},
  issn={1463-9262},
  journal={Green Chemistry},
  pages={1874--1878},
  author={Pingen, Dennis and Zimmerer, Julia and Klinkenberg, Nele and Mecking, Stefan}
}

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