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Adsorption and Decomposition of DMMP on Size‐Selected (WO<sub>3</sub>)<sub>3</sub> Clusters

Adsorption and Decomposition of DMMP on Size‐Selected (WO3)3 Clusters

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TANG, Xin, Zachary HICKS, Gerd GANTEFÖR, Bryan W. EICHHORN, Kit H. BOWEN, 2018. Adsorption and Decomposition of DMMP on Size‐Selected (WO3)3 Clusters. In: ChemistrySelect. 3(13), pp. 3718-3721. eISSN 2365-6549. Available under: doi: 10.1002/slct.201800229

@article{Tang2018-04-09Adsor-42300, title={Adsorption and Decomposition of DMMP on Size‐Selected (WO3)3 Clusters}, year={2018}, doi={10.1002/slct.201800229}, number={13}, volume={3}, journal={ChemistrySelect}, pages={3718--3721}, author={Tang, Xin and Hicks, Zachary and Ganteför, Gerd and Eichhorn, Bryan W. and Bowen, Kit H.} }

2018-05-11T08:55:47Z Hicks, Zachary Tang, Xin Hicks, Zachary Eichhorn, Bryan W. eng 2018-05-11T08:55:47Z Eichhorn, Bryan W. Bowen, Kit H. Tang, Xin Adsorption and Decomposition of DMMP on Size‐Selected (WO<sub>3</sub>)<sub>3</sub> Clusters Bowen, Kit H. The adsorption and decomposition behaviors of dimethyl methylphosphate (DMMP) on size‐selected (WO<sub>3</sub>)<sub>3</sub> clusters were studied by a combination of X‐ray Photoelectron Spectroscopy (XPS) and Temperature Programmed Reaction (TPR). The fate of DMMP adsorbed on (WO<sub>3</sub>)<sub>3</sub> clusters was found to be very similar to its fate on (MoO<sub>3</sub>)<sub>3</sub>. In contrast to DMMP on (MoO<sub>3</sub>)<sub>3</sub>, however, dimethyl ether was observed as a product in the reaction of DMMP with (WO<sub>3</sub>)<sub>3</sub>, in addition to methanol, due to the higher Lewis acidity of (WO<sub>3</sub>)<sub>3</sub> clusters as compared to (MoO<sub>3</sub>)<sub>3</sub>. Ganteför, Gerd Ganteför, Gerd 2018-04-09

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