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Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-Oil-Derived Long-Chain Diisocyanates

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Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-Oil-Derived Long-Chain Diisocyanates

Type of Publication: Journal article
Publication status: Published
URI (citable link): http://nbn-resolving.de/urn:nbn:de:bsz:352-2-1r15w60hm6cj02
Author: Schemmer, Brigitta; Kronenbitter, Cathrin; Mecking, Stefan
Year of publication: 2018
Published in: Macromolecular Materials and Engineering ; 303 (2018), 4. - 1700416. - ISSN 0003-3146. - eISSN 1439-2054
DOI (citable link): https://dx.doi.org/10.1002/mame.201700416
Summary:
Novel plant-oil-derived long-chain (C19 and C23) α,ω-diisocyanates, optionally in combination with the corresponding long-chain diols, provide entirely aliphatic hard segments in segmented thermoplastic polyurethane elastomers (TPUs), with carbohydrate-based poly(trimethylene glycol) soft segments. Compared to materials based on a mid-chain monomer analog, phase separation is higher due to an increased flexibility of the aliphatic segments. Although melting points are slightly lower than for HDPE, the long-chain TPU's solid-state structure is still dominated by hydrogen-bonding.
Subject (DDC): 540 Chemistry
Link to License: In Copyright
Bibliography of Konstanz: Yes
Refereed: Yes

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SCHEMMER, Brigitta, Cathrin KRONENBITTER, Stefan MECKING, 2018. Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-Oil-Derived Long-Chain Diisocyanates. In: Macromolecular Materials and Engineering. 303(4), 1700416. ISSN 0003-3146. eISSN 1439-2054. Available under: doi: 10.1002/mame.201700416

@article{Schemmer2018-04Therm-41769, title={Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-Oil-Derived Long-Chain Diisocyanates}, year={2018}, doi={10.1002/mame.201700416}, number={4}, volume={303}, issn={0003-3146}, journal={Macromolecular Materials and Engineering}, author={Schemmer, Brigitta and Kronenbitter, Cathrin and Mecking, Stefan}, note={Article Number: 1700416} }

terms-of-use 2018-03-14T09:01:02Z Schemmer, Brigitta Schemmer, Brigitta eng Kronenbitter, Cathrin Novel plant-oil-derived long-chain (C<sub>19</sub> and C<sub>23</sub>) α,ω-diisocyanates, optionally in combination with the corresponding long-chain diols, provide entirely aliphatic hard segments in segmented thermoplastic polyurethane elastomers (TPUs), with carbohydrate-based poly(trimethylene glycol) soft segments. Compared to materials based on a mid-chain monomer analog, phase separation is higher due to an increased flexibility of the aliphatic segments. Although melting points are slightly lower than for HDPE, the long-chain TPU's solid-state structure is still dominated by hydrogen-bonding. 2018-04 Mecking, Stefan Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-Oil-Derived Long-Chain Diisocyanates Kronenbitter, Cathrin Mecking, Stefan 2018-03-14T09:01:02Z

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