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From Oleo Chemicals to Polymer : Bis-hydroaminomethylation as a Tool for the Preparation of a Synthetic Polymer from Renewables

From Oleo Chemicals to Polymer : Bis-hydroaminomethylation as a Tool for the Preparation of a Synthetic Polymer from Renewables

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SEIDENSTICKER, Thomas, Hanna BUSCH, Christopher DIEDERICHS, Jork Jonas VON DINCKLAGE, Andreas J. VORHOLT, 2016. From Oleo Chemicals to Polymer : Bis-hydroaminomethylation as a Tool for the Preparation of a Synthetic Polymer from Renewables. In: ChemCatChem. 8(18), pp. 2890-2893. ISSN 1867-3880. eISSN 1867-3899

@article{Seidensticker2016Chemi-37776, title={From Oleo Chemicals to Polymer : Bis-hydroaminomethylation as a Tool for the Preparation of a Synthetic Polymer from Renewables}, year={2016}, doi={10.1002/cctc.201600629}, number={18}, volume={8}, issn={1867-3880}, journal={ChemCatChem}, pages={2890--2893}, author={Seidensticker, Thomas and Busch, Hanna and Diederichs, Christopher and von Dincklage, Jork Jonas and Vorholt, Andreas J.} }

Resource-efficient bis-hydroaminomethylation of the castor oil derived renewables methyl 10-undecenoate and 10-undecene-1-ol with piperazine furnished linear, bifunctional molecules. A structured and sustainable path towards a novel polyester from these monomers was developed. Key to success was the selective crystallization of the linear product directly from the crude reaction mixture in >98 % purity. Additionally, with this methodology, the homogeneous Rh catalyst was retained in the supernatant and was successfully recycled. Finally, polycondensation yielded a novel piperazine-linked polyester. 2017-02-28T15:08:25Z von Dincklage, Jork Jonas Busch, Hanna 2016 Vorholt, Andreas J. Busch, Hanna von Dincklage, Jork Jonas eng Seidensticker, Thomas Seidensticker, Thomas Diederichs, Christopher From Oleo Chemicals to Polymer : Bis-hydroaminomethylation as a Tool for the Preparation of a Synthetic Polymer from Renewables Vorholt, Andreas J. 2017-02-28T15:08:25Z Diederichs, Christopher

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