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Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines

Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines

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ECKERMANN, Ruben, Michael BREUNIG, Tanja GAICH, 2016. Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines. In: Chemical Communications : ChemComm. 52(76), pp. 11363-11365. ISSN 0009-241X. eISSN 1364-548X

@article{Eckermann2016Forma-37437, title={Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines}, year={2016}, doi={10.1039/c6cc06125g}, number={76}, volume={52}, issn={0009-241X}, journal={Chemical Communications : ChemComm}, pages={11363--11365}, author={Eckermann, Ruben and Breunig, Michael and Gaich, Tanja} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/37437"> <dc:contributor>Breunig, Michael</dc:contributor> <dc:language>eng</dc:language> <dcterms:title>Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines</dcterms:title> <dc:contributor>Eckermann, Ruben</dc:contributor> <dc:contributor>Gaich, Tanja</dc:contributor> <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/37437"/> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-02-15T11:19:18Z</dcterms:available> <dc:creator>Gaich, Tanja</dc:creator> <dcterms:rights rdf:resource="http://nbn-resolving.de/urn:nbn:de:bsz:352-20150914100631302-4485392-8"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-02-15T11:19:18Z</dc:date> <dcterms:abstract xml:lang="eng">For decades, akuammiline alkaloids have attracted synthetic chemists due to their intriguing molecular architecture. Among the different structural elements embedded in their carboskeleton, the methanoquinolizidine system constitutes the signature structural element of this alkaloid family. Herein, we describe a novel synthetic access to this system which relies on a [2,3]-Stevens rearrangement and results in the formal synthesis of strictamine.</dcterms:abstract> <dc:creator>Breunig, Michael</dc:creator> <dc:creator>Eckermann, Ruben</dc:creator> <dcterms:issued>2016</dcterms:issued> </rdf:Description> </rdf:RDF>

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