Type of Publication: | Journal article |
Publication status: | Published |
Author: | Meyer, Nadine; Schucht, Heike; Lehmann, Christian W.; Weibert, Bernhard; Winter, Rainer F.; Mohr, Fabian |
Year of publication: | 2017 |
Published in: | European Journal of Inorganic Chemistry ; 2017 (2017), 2. - pp. 521-526. - ISSN 1434-1948. - eISSN 1099-0682 |
DOI (citable link): | https://dx.doi.org/10.1002/ejic.201601458 |
Summary: |
A family of aurated ferrocenes was prepared by a transmetallation reaction using ferroceneboronic acid derivatives. With this method, multimetallic ferrocenyl complexes [FcAu(PPh3)] {Fc = (η5-C5H4)FeCp} and [(µ-P-P)(AuFc)2] {P-P = dppe, dppf}, as well as 1,1′-diaurated ferrocenes [Fe(η5-C5H4AuPPh3)2] and [Fe{(η5-C5H4Au)}2(µ-P-P)] {P-P = dppe, dppf}, were obtained in high yields as air-stable orange materials. The compounds were characterised by spectroscopic methods, cyclic voltammetry and single-crystal X-ray diffraction. The reactivity of the dinuclear gold(I) complex in oxidative addition reactions is also reported.
|
Subject (DDC): | 540 Chemistry |
Bibliography of Konstanz: | Yes |
Files | Size | Format | View |
---|---|---|---|
There are no files associated with this item. |
MEYER, Nadine, Heike SCHUCHT, Christian W. LEHMANN, Bernhard WEIBERT, Rainer F. WINTER, Fabian MOHR, 2017. Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes. In: European Journal of Inorganic Chemistry. 2017(2), pp. 521-526. ISSN 1434-1948. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201601458
@article{Meyer2017Multi-36870, title={Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes}, year={2017}, doi={10.1002/ejic.201601458}, number={2}, volume={2017}, issn={1434-1948}, journal={European Journal of Inorganic Chemistry}, pages={521--526}, author={Meyer, Nadine and Schucht, Heike and Lehmann, Christian W. and Weibert, Bernhard and Winter, Rainer F. and Mohr, Fabian} }
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/36870"> <dc:creator>Lehmann, Christian W.</dc:creator> <dc:contributor>Lehmann, Christian W.</dc:contributor> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:contributor>Winter, Rainer F.</dc:contributor> <dc:creator>Winter, Rainer F.</dc:creator> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-01-20T13:52:55Z</dc:date> <dc:contributor>Meyer, Nadine</dc:contributor> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:contributor>Mohr, Fabian</dc:contributor> <dc:contributor>Weibert, Bernhard</dc:contributor> <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/36870"/> <dc:creator>Weibert, Bernhard</dc:creator> <dcterms:issued>2017</dcterms:issued> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dcterms:abstract xml:lang="eng">A family of aurated ferrocenes was prepared by a transmetallation reaction using ferroceneboronic acid derivatives. With this method, multimetallic ferrocenyl complexes [FcAu(PPh3)] {Fc = (η5-C5H4)FeCp} and [(µ-P-P)(AuFc)2] {P-P = dppe, dppf}, as well as 1,1′-diaurated ferrocenes [Fe(η5-C5H4AuPPh3)2] and [Fe{(η5-C5H4Au)}2(µ-P-P)] {P-P = dppe, dppf}, were obtained in high yields as air-stable orange materials. The compounds were characterised by spectroscopic methods, cyclic voltammetry and single-crystal X-ray diffraction. The reactivity of the dinuclear gold(I) complex in oxidative addition reactions is also reported.</dcterms:abstract> <dc:contributor>Schucht, Heike</dc:contributor> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-01-20T13:52:55Z</dcterms:available> <dc:creator>Mohr, Fabian</dc:creator> <dc:language>eng</dc:language> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dc:creator>Schucht, Heike</dc:creator> <dc:creator>Meyer, Nadine</dc:creator> <dcterms:title>Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes</dcterms:title> </rdf:Description> </rdf:RDF>