Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes
| Type of Publication: | Journal article |
| Publication status: | Published |
| Author: | Meyer, Nadine; Schucht, Heike; Lehmann, Christian W.; Weibert, Bernhard; Winter, Rainer F.; Mohr, Fabian |
| Year of publication: | 2017 |
| Published in: | European Journal of Inorganic Chemistry ; 2017 (2017), 2. - pp. 521-526. - ISSN 1434-1948. - eISSN 1099-0682 |
| DOI (citable link): | https://dx.doi.org/10.1002/ejic.201601458 |
| Summary: |
A family of aurated ferrocenes was prepared by a transmetallation reaction using ferroceneboronic acid derivatives. With this method, multimetallic ferrocenyl complexes [FcAu(PPh3)] {Fc = (η5-C5H4)FeCp} and [(µ-P-P)(AuFc)2] {P-P = dppe, dppf}, as well as 1,1′-diaurated ferrocenes [Fe(η5-C5H4AuPPh3)2] and [Fe{(η5-C5H4Au)}2(µ-P-P)] {P-P = dppe, dppf}, were obtained in high yields as air-stable orange materials. The compounds were characterised by spectroscopic methods, cyclic voltammetry and single-crystal X-ray diffraction. The reactivity of the dinuclear gold(I) complex in oxidative addition reactions is also reported.
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| Subject (DDC): | 540 Chemistry |
| Bibliography of Konstanz: | Yes |
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MEYER, Nadine, Heike SCHUCHT, Christian W. LEHMANN, Bernhard WEIBERT, Rainer F. WINTER, Fabian MOHR, 2017. Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes. In: European Journal of Inorganic Chemistry. 2017(2), pp. 521-526. ISSN 1434-1948. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201601458
@article{Meyer2017Multi-36870, title={Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes}, year={2017}, doi={10.1002/ejic.201601458}, number={2}, volume={2017}, issn={1434-1948}, journal={European Journal of Inorganic Chemistry}, pages={521--526}, author={Meyer, Nadine and Schucht, Heike and Lehmann, Christian W. and Weibert, Bernhard and Winter, Rainer F. and Mohr, Fabian} }
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