Type of Publication: | Journal article |
Publication status: | Published |
Author: | Leicht, Hannes; Göttker-Schnetmann, Inigo; Mecking, Stefan |
Year of publication: | 2016 |
Published in: | ACS Macro Letters ; 5 (2016), 6. - pp. 777-780. - ISSN 2161-1653. - eISSN 2161-1653 |
DOI (citable link): | https://dx.doi.org/10.1021/acsmacrolett.6b00321 |
Summary: |
[(Mesitylene)nickel(allyl)+][BArF4–] (Ni-1) catalyzes the 1,4-cis selective copolymerization of isoprene and 1,3-butadiene with 15 (RO)3Si-, R2N-, RSO2-, RSO2NH-, and (RO)2B-functionalized 1,3-dienes. Incorporation of the functionalized 1,3-diene occurs very efficiently with high comonomer conversions, as observed, for example, for copolymerizations of 1,3-butadiene with (EtO)3Si(CH2)3C(═CH2)CH═CH2 (1), PhS(O)2(CH2)3C(═CH2)–CH═CH2 (7), or (pinB)C(═CH2)C(CH3)═CH2 (15), while copolymerization rates vary from strongly to slightly decreased when compared to butadiene homopolymerizations.
|
Subject (DDC): | 540 Chemistry |
Bibliography of Konstanz: | Yes |
Files | Size | Format | View |
---|---|---|---|
There are no files associated with this item. |
LEICHT, Hannes, Inigo GÖTTKER-SCHNETMANN, Stefan MECKING, 2016. Stereoselective Copolymerization of Butadiene and Functionalized 1,3-Dienes. In: ACS Macro Letters. 5(6), pp. 777-780. ISSN 2161-1653. eISSN 2161-1653. Available under: doi: 10.1021/acsmacrolett.6b00321
@article{Leicht2016-06-21Stere-34765, title={Stereoselective Copolymerization of Butadiene and Functionalized 1,3-Dienes}, year={2016}, doi={10.1021/acsmacrolett.6b00321}, number={6}, volume={5}, issn={2161-1653}, journal={ACS Macro Letters}, pages={777--780}, author={Leicht, Hannes and Göttker-Schnetmann, Inigo and Mecking, Stefan} }