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Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?

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Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?

Type of Publication: Journal article
Publication status: Published
URI (citable link): http://nbn-resolving.de/urn:nbn:de:bsz:352-0-326695
Author: Nitsch, Jörn; Lacemon, Frederick; Lorbach, Andreas; Eichhorn, Antonius; Cisnetti, Federico; Steffen, Andreas
Year of publication: 2016
Published in: Chemical Communications : ChemComm ; 52 (2016), 14. - pp. 2932-2935. - ISSN 1359-7345. - eISSN 1364-548X
DOI (citable link): https://dx.doi.org/10.1039/C5CC09659F
Summary:
This case study on a series of monomeric, dimeric and polymeric CuI chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T1 ↔ S1 and T1 → S0, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T1 emitters.
Subject (DDC): 540 Chemistry
Link to License: In Copyright
Bibliography of Konstanz: Yes
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NITSCH, Jörn, Frederick LACEMON, Andreas LORBACH, Antonius EICHHORN, Federico CISNETTI, Andreas STEFFEN, 2016. Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?. In: Chemical Communications : ChemComm. 52(14), pp. 2932-2935. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C5CC09659F

@article{Nitsch2016Cupro-33981, title={Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?}, year={2016}, doi={10.1039/C5CC09659F}, number={14}, volume={52}, issn={1359-7345}, journal={Chemical Communications : ChemComm}, pages={2932--2935}, author={Nitsch, Jörn and Lacemon, Frederick and Lorbach, Andreas and Eichhorn, Antonius and Cisnetti, Federico and Steffen, Andreas} }

terms-of-use Steffen, Andreas 2016-05-18T09:20:05Z 2016 Cisnetti, Federico Cisnetti, Federico Nitsch, Jörn Eichhorn, Antonius Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF? Lorbach, Andreas This case study on a series of monomeric, dimeric and polymeric Cu<sup>I</sup> chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T<sub>1</sub> ↔ S<sub>1</sub> and T<sub>1</sub> → S<sub>0</sub>, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T<sub>1</sub> emitters. Lorbach, Andreas Lacemon, Frederick eng Eichhorn, Antonius 2016-05-18T09:20:05Z Nitsch, Jörn Steffen, Andreas Lacemon, Frederick

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