Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?
Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?
Date
2016
Authors
Editors
Journal ISSN
Electronic ISSN
ISBN
Bibliographical data
Publisher
Series
URI (citable link)
DOI (citable link)
International patent number
Link to the license
EU project number
Project
Open Access publication
Collections
Title in another language
Publication type
Journal article
Publication status
Published
Published in
Chemical Communications : ChemComm ; 52 (2016), 14. - pp. 2932-2935. - ISSN 1359-7345. - eISSN 1364-548X
Abstract
This case study on a series of monomeric, dimeric and polymeric CuI chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T1 ↔ S1 and T1 → S0, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T1 emitters.
Summary in another language
Subject (DDC)
540 Chemistry
Keywords
Conference
Review
undefined / . - undefined, undefined. - (undefined; undefined)
Cite This
ISO 690
NITSCH, Jörn, Frederick LACEMON, Andreas LORBACH, Antonius EICHHORN, Federico CISNETTI, Andreas STEFFEN, 2016. Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?. In: Chemical Communications : ChemComm. 52(14), pp. 2932-2935. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C5CC09659FBibTex
@article{Nitsch2016Cupro-33981, year={2016}, doi={10.1039/C5CC09659F}, title={Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?}, number={14}, volume={52}, issn={1359-7345}, journal={Chemical Communications : ChemComm}, pages={2932--2935}, author={Nitsch, Jörn and Lacemon, Frederick and Lorbach, Andreas and Eichhorn, Antonius and Cisnetti, Federico and Steffen, Andreas} }
RDF
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/33981"> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/33981/1/Nitsch_0-326695.pdf"/> <dc:creator>Lacemon, Frederick</dc:creator> <dcterms:issued>2016</dcterms:issued> <foaf:homepage rdf:resource="http://localhost:8080/"/> <dc:language>eng</dc:language> <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/> <dcterms:abstract xml:lang="eng">This case study on a series of monomeric, dimeric and polymeric Cu<sup>I</sup> chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T<sub>1</sub> ↔ S<sub>1</sub> and T<sub>1</sub> → S<sub>0</sub>, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T<sub>1</sub> emitters.</dcterms:abstract> <dc:contributor>Eichhorn, Antonius</dc:contributor> <dcterms:title>Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?</dcterms:title> <dc:creator>Nitsch, Jörn</dc:creator> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-05-18T09:20:05Z</dc:date> <dc:contributor>Lacemon, Frederick</dc:contributor> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/33981/1/Nitsch_0-326695.pdf"/> <dc:contributor>Lorbach, Andreas</dc:contributor> <dc:creator>Lorbach, Andreas</dc:creator> <dc:contributor>Nitsch, Jörn</dc:contributor> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-05-18T09:20:05Z</dcterms:available> <dc:creator>Steffen, Andreas</dc:creator> <dc:creator>Eichhorn, Antonius</dc:creator> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/33981"/> <dc:contributor>Steffen, Andreas</dc:contributor> <dc:rights>terms-of-use</dc:rights> <dc:contributor>Cisnetti, Federico</dc:contributor> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/> <dc:creator>Cisnetti, Federico</dc:creator> </rdf:Description> </rdf:RDF>
Internal note
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Examination date of dissertation
Method of financing
Comment on publication
Alliance license
Corresponding Authors der Uni Konstanz vorhanden
International Co-Authors
Bibliography of Konstanz
Yes