Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?

Nitsch, Jörn; Lacemon, Frederick; Lorbach, Andreas; Eichhorn, Antonius; Cisnetti, Federico; Steffen, Andreas

doi:10.1039/C5CC09659F

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Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?

Publikationstyp:	Zeitschriftenartikel
Publikationsstatus:	Published
URI (zitierfähiger Link):	http://nbn-resolving.de/urn:nbn:de:bsz:352-0-326695
Autor/innen:	Nitsch, Jörn; Lacemon, Frederick; Lorbach, Andreas; Eichhorn, Antonius; Cisnetti, Federico; Steffen, Andreas
Erscheinungsjahr:	2016
Erschienen in:	Chemical Communications : ChemComm ; 52 (2016), 14. - S. 2932-2935. - ISSN 1359-7345. - eISSN 1364-548X
DOI (zitierfähiger Link):	https://dx.doi.org/10.1039/C5CC09659F
Zusammenfassung:	This case study on a series of monomeric, dimeric and polymeric Cu^I chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T₁ ↔ S₁ and T₁ → S₀, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T₁ emitters.
Fachgebiet (DDC):	540 Chemie
Link zur Lizenz:	Nutzungsbedingungen
Universitätsbibliographie:	Ja
Dieser Beitrag ist im Zusammenhang des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.

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NITSCH, Jörn, Frederick LACEMON, Andreas LORBACH, Antonius EICHHORN, Federico CISNETTI, Andreas STEFFEN, 2016. Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?. In: Chemical Communications : ChemComm. 52(14), pp. 2932-2935. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C5CC09659F

@article{Nitsch2016Cupro-33981, title={Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?}, year={2016}, doi={10.1039/C5CC09659F}, number={14}, volume={52}, issn={1359-7345}, journal={Chemical Communications : ChemComm}, pages={2932--2935}, author={Nitsch, Jörn and Lacemon, Frederick and Lorbach, Andreas and Eichhorn, Antonius and Cisnetti, Federico and Steffen, Andreas} }

terms-of-use Steffen, Andreas 2016-05-18T09:20:05Z 2016 Cisnetti, Federico Cisnetti, Federico Nitsch, Jörn Eichhorn, Antonius Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF? Lorbach, Andreas This case study on a series of monomeric, dimeric and polymeric CuI chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T1 ↔ S1 and T1 → S0, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T1 emitters. Lorbach, Andreas Lacemon, Frederick eng Eichhorn, Antonius 2016-05-18T09:20:05Z Nitsch, Jörn Steffen, Andreas Lacemon, Frederick