Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?

Nitsch, Jörn; Lacemon, Frederick; Lorbach, Andreas; Eichhorn, Antonius; Cisnetti, Federico; Steffen, Andreas

Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?

Files

Nitsch_0-326695.pdf(2.01 MB)

Date

2016

Authors

Nitsch, Jörn

Lacemon, Frederick

Lorbach, Andreas

Eichhorn, Antonius

Cisnetti, Federico

Steffen, Andreas

Publication type

Journal article

Publication status

Published

Published in

Chemical Communications : ChemComm ; 52 (2016), 14. - pp. 2932-2935. - ISSN 1359-7345. - eISSN 1364-548X

Abstract

This case study on a series of monomeric, dimeric and polymeric Cu^I chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T₁ ↔ S₁ and T₁ → S₀, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T₁ emitters.

Subject (DDC)

540 Chemistry

Cite This

ISO 690

NITSCH, Jörn, Frederick LACEMON, Andreas LORBACH, Antonius EICHHORN, Federico CISNETTI, Andreas STEFFEN, 2016. Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?. In: Chemical Communications : ChemComm. 52(14), pp. 2932-2935. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C5CC09659F

BibTex

@article{Nitsch2016Cupro-33981,
  year={2016},
  doi={10.1039/C5CC09659F},
  title={Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?},
  number={14},
  volume={52},
  issn={1359-7345},
  journal={Chemical Communications : ChemComm},
  pages={2932--2935},
  author={Nitsch, Jörn and Lacemon, Frederick and Lorbach, Andreas and Eichhorn, Antonius and Cisnetti, Federico and Steffen, Andreas}
}

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Bibliography of Konstanz

Yes