Negative Diamagnetic Anisotropy and Birefringence of Cellulose Nanocrystals


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FRKA-PETESIC, Bruno, Junji SUGIYAMA, Satoshi KIMURA, Henri CHANZY, Georg MARET, 2015. Negative Diamagnetic Anisotropy and Birefringence of Cellulose Nanocrystals. In: Macromolecules. 48(24), pp. 8844-8857. ISSN 0024-9297. eISSN 1520-5835. Available under: doi: 10.1021/acs.macromol.5b02201

@article{FrkaPetesic2015Negat-32602, title={Negative Diamagnetic Anisotropy and Birefringence of Cellulose Nanocrystals}, year={2015}, doi={10.1021/acs.macromol.5b02201}, number={24}, volume={48}, issn={0024-9297}, journal={Macromolecules}, pages={8844--8857}, author={Frka-Petesic, Bruno and Sugiyama, Junji and Kimura, Satoshi and Chanzy, Henri and Maret, Georg} }

<rdf:RDF xmlns:dcterms="" xmlns:dc="" xmlns:rdf="" xmlns:bibo="" xmlns:dspace="" xmlns:foaf="" xmlns:void="" xmlns:xsd="" > <rdf:Description rdf:about=""> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dc:contributor>Sugiyama, Junji</dc:contributor> <dc:contributor>Chanzy, Henri</dc:contributor> <dc:contributor>Maret, Georg</dc:contributor> <dc:date rdf:datatype="">2016-01-15T12:40:39Z</dc:date> <dc:creator>Chanzy, Henri</dc:creator> <dc:contributor>Frka-Petesic, Bruno</dc:contributor> <dcterms:abstract xml:lang="eng">We report magnetic birefringence measurements up to high fields (17.5 T) of dilute aqueous suspensions of rod-like cellulose nanocrystals with well characterized distributions of lengths, widths and thicknesses. We compare these data with three models, one with colinear (1), one with perpendicular cylindrically symmetric tensors for diamagnetic susceptibility and refractive index (2) and one with biaxial diamagnetic anisotropy (3). We find that taking into account polydispersities of length, width, and thickness is essential for accurate fitting and that model 1 is the most appropriate, presumably because of the twisting of the suspended nanocrystal along their long axis. The best-fitted susceptibility anisotropy was Δχz(xy) = χzz–(χxx+χyy)/2 = −2.44 × 10–6 when considering only the crystalline core of nanocrystals and, more appropriately, Δχz(xy) = −0.95 × 10–6 when including crystalline core and skin. The latter value is slightly higher than Δχz(xy) = −0.68(5) × 10–6 deduced from estimations using Pascal’s additivity law. The specific birefringence of the nanocrystals in water was found to be δn0 = +0.120(2), which is well accounted for by the intrinsic birefringence of crystalline cellulose (δn0intr = n∥–n⊥ = +0.0744) and the birefringence arising from the slender shape of nanocrystals.</dcterms:abstract> <dspace:isPartOfCollection rdf:resource=""/> <dc:creator>Kimura, Satoshi</dc:creator> <dc:contributor>Kimura, Satoshi</dc:contributor> <dc:creator>Frka-Petesic, Bruno</dc:creator> <dcterms:isPartOf rdf:resource=""/> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:language>eng</dc:language> <dc:creator>Maret, Georg</dc:creator> <dcterms:issued>2015</dcterms:issued> <dcterms:available rdf:datatype="">2016-01-15T12:40:39Z</dcterms:available> <bibo:uri rdf:resource=""/> <dcterms:title>Negative Diamagnetic Anisotropy and Birefringence of Cellulose Nanocrystals</dcterms:title> <dc:creator>Sugiyama, Junji</dc:creator> </rdf:Description> </rdf:RDF>

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