Photoelectron spectroscopy of boron aluminum hydride cluster anions


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WANG, Haopeng, Xinxing ZHANG, Yeon Jae KO, Gerd GANTEFOER, Kit H. BOWEN, Xiang LI, Boggavarapu KIRAN, Anil K. KANDALAM, 2014. Photoelectron spectroscopy of boron aluminum hydride cluster anions. In: The Journal of Chemical Physics. 140(16), 164317. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4871884

@article{Wang2014Photo-30940, title={Photoelectron spectroscopy of boron aluminum hydride cluster anions}, year={2014}, doi={10.1063/1.4871884}, number={16}, volume={140}, issn={0021-9606}, journal={The Journal of Chemical Physics}, author={Wang, Haopeng and Zhang, Xinxing and Ko, Yeon Jae and Gantefoer, Gerd and Bowen, Kit H. and Li, Xiang and Kiran, Boggavarapu and Kandalam, Anil K.}, note={Article Number: 164317} }

Li, Xiang Ko, Yeon Jae Wang, Haopeng 2015-05-13T07:25:20Z Bowen, Kit H. Kandalam, Anil K. Gantefoer, Gerd Kiran, Boggavarapu Wang, Haopeng eng 2014 Gantefoer, Gerd Zhang, Xinxing Zhang, Xinxing Ko, Yeon Jae Boron aluminum hydride clusters are studied through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations. Boron aluminum hydride cluster anions, B<sub>x</sub>Al<sub>y</sub>H<sub>z</sub><sup>-</sup>, were generated in a pulsed arc cluster ionization source and identified by time-of-flight mass spectrometry. After mass selection, their photoelectron spectra were measured by a magnetic bottle-type electron energy analyzer. The resultant photoelectron spectra as well as calculations on a selected series of stoichiometries reveal significant geometrical changes upon substitution of aluminum atoms by boron atoms. Li, Xiang Kiran, Boggavarapu Photoelectron spectroscopy of boron aluminum hydride cluster anions Kandalam, Anil K. 2015-05-13T07:25:20Z Bowen, Kit H.

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