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Probing the magnetic moments of [Mn<sup>III</sup><sub>6</sub>Cr<sup>III</sup>]<sup>3+</sup>single-moleculemagnets : A cross comparison of XMCD and spin-resolvedelectron spectroscopy

Probing the magnetic moments of [MnIII6CrIII]3+single-moleculemagnets : A cross comparison of XMCD and spin-resolvedelectron spectroscopy

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Prüfsumme: MD5:1112bd321df06988bbbf77dc46fd9633

HELMSTEDT, Andreas, Niklas DOHMEIER, Norbert MÜLLER, Aaron GRYZIA, Armin BRECHLING, Ulrich HEINZMANN, Veronika HOEKE, Erich KRICKEMEYER, Thorsten GLASER, Philipp LEICHT, Mikhail FONIN, Thomas TIETZE, Loïc JOLY, Karsten KUEPPER, 2015. Probing the magnetic moments of [MnIII6CrIII]3+single-moleculemagnets : A cross comparison of XMCD and spin-resolvedelectron spectroscopy. In: Journal of Electron Spectroscopy and Related Phenomena. 198, pp. 12-19. ISSN 0368-2048. eISSN 1873-2526. Available under: doi: 10.1016/j.elspec.2014.11.005

@article{Helmstedt2015Probi-30829, title={Probing the magnetic moments of [MnIII6CrIII]3+single-moleculemagnets : A cross comparison of XMCD and spin-resolvedelectron spectroscopy}, year={2015}, doi={10.1016/j.elspec.2014.11.005}, volume={198}, issn={0368-2048}, journal={Journal of Electron Spectroscopy and Related Phenomena}, pages={12--19}, author={Helmstedt, Andreas and Dohmeier, Niklas and Müller, Norbert and Gryzia, Aaron and Brechling, Armin and Heinzmann, Ulrich and Hoeke, Veronika and Krickemeyer, Erich and Glaser, Thorsten and Leicht, Philipp and Fonin, Mikhail and Tietze, Thomas and Joly, Loïc and Kuepper, Karsten} }

Heinzmann, Ulrich Heinzmann, Ulrich Gryzia, Aaron Joly, Loïc Helmstedt, Andreas Brechling, Armin Kuepper, Karsten eng Leicht, Philipp Glaser, Thorsten 2015-04-29T08:32:55Z Krickemeyer, Erich Dohmeier, Niklas Tietze, Thomas Hoeke, Veronika Müller, Norbert Gryzia, Aaron Fonin, Mikhail Krickemeyer, Erich Joly, Loïc 2015-04-29T08:32:55Z Kuepper, Karsten Dohmeier, Niklas Helmstedt, Andreas Glaser, Thorsten Probing the magnetic moments of [Mn<sup>III</sup><sub>6</sub>Cr<sup>III</sup>]<sup>3+</sup>single-moleculemagnets : A cross comparison of XMCD and spin-resolvedelectron spectroscopy Fonin, Mikhail Müller, Norbert Brechling, Armin Tietze, Thomas Leicht, Philipp Single-molecule magnets (SMM) of the [Mn<sup>III</sup><sub>6</sub>Cr<sup>III</sup>]<sup>3+ </sup>structural type prepared on Si and gold-coated glass substrates have been investigated by spin-resolved electron spectroscopy (SPES) and X-ray magnetic circular dichroism (XMCD) at the Mn L<sub>3,2</sub> edge and in addition by XMCD at the Cr L<sub>3,2</sub> edge using synchrotron radiation. Differences between the two methods are discussed. Despite its severe limitations for 3d transition metals, a spin sum rule evaluation is nevertheless performed for the MnIII centres in the [Mn<sup>III</sup><sub>6</sub>Cr<sup>III</sup>]<sup>3+</sup> SMM to provide a simple means of comparing XMCD and spin-resolved electron spectroscopy results. 2015 Hoeke, Veronika

Dateiabrufe seit 29.04.2015 (Informationen über die Zugriffsstatistik)

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