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Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity

Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity

Type of Publication: Journal article
Author: Amirkhanov, Oleksiy V.; Moroz, Olesia V.; Znovjyak, Kateryna O.; Silva, Tetiana Yu.; Penkova, Larysa V.; Yushchenko, Tetyana; Szyrwiel, Lukasz; Konovalova, Irina S.; Dyakonenko, Viktoriya; Shishkin, Oleg V.; Amirkhanov, Vadimir M.
Year of publication: 2014
Published in: European Journal of Inorganic Chemistry ; 2014 (2014), 23. - pp. 3720-3730. - ISSN 0009-2940. - eISSN 1099-0682
DOI (citable link): https://dx.doi.org/10.1002/ejic.201402224
Summary:
The reaction of Salen-like ZnII and NiII precursors with carbacylamidophosphate lanthanide moieties yields six new types of 3d–4f compounds. The complexes were characterized by means of 1H, 31P NMR and IR spectroscopy, elemental analysis, ESI mass spectrometry, and X-ray diffraction analysis. Depending on the Schiff base ligands, the NiII ion adopts either a square-planar or an octahedral geometry, whereas the ZnII ion has a tetragonal-pyramidal geometry. The coordination number of lanthanides is nine or ten. Hydrolytic activities of some heterobimetallic Zn–Ln and Ni–Ln coordination compounds in the reaction of intramolecular hydrolytic degradation of the 2-(hydroxypropyl)-p-nitrophenyl phosphate were investigated.
Subject (DDC): 540 Chemistry
Keywords: Heterometallic complexes, ­Kinetics, Lanthanide, N,O-ligands, Structure elucidation

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AMIRKHANOV, Oleksiy V., Olesia V. MOROZ, Kateryna O. ZNOVJYAK, Tetiana Yu. SILVA, Larysa V. PENKOVA, Tetyana YUSHCHENKO, Lukasz SZYRWIEL, Irina S. KONOVALOVA, Viktoriya DYAKONENKO, Oleg V. SHISHKIN, Vadimir M. AMIRKHANOV, 2014. Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity. In: European Journal of Inorganic Chemistry. 2014(23), pp. 3720-3730. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201402224

@article{Amirkhanov2014Heter-29582, title={Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity}, year={2014}, doi={10.1002/ejic.201402224}, number={23}, volume={2014}, issn={0009-2940}, journal={European Journal of Inorganic Chemistry}, pages={3720--3730}, author={Amirkhanov, Oleksiy V. and Moroz, Olesia V. and Znovjyak, Kateryna O. and Silva, Tetiana Yu. and Penkova, Larysa V. and Yushchenko, Tetyana and Szyrwiel, Lukasz and Konovalova, Irina S. and Dyakonenko, Viktoriya and Shishkin, Oleg V. and Amirkhanov, Vadimir M.} }

Znovjyak, Kateryna O. Silva, Tetiana Yu. Dyakonenko, Viktoriya Penkova, Larysa V. Konovalova, Irina S. 2014 Szyrwiel, Lukasz Dyakonenko, Viktoriya Amirkhanov, Oleksiy V. 2015-01-21T15:31:21Z Konovalova, Irina S. Moroz, Olesia V. Szyrwiel, Lukasz Znovjyak, Kateryna O. Penkova, Larysa V. Amirkhanov, Oleksiy V. Yushchenko, Tetyana Amirkhanov, Vadimir M. eng Silva, Tetiana Yu. Shishkin, Oleg V. Yushchenko, Tetyana Amirkhanov, Vadimir M. Moroz, Olesia V. 2015-01-21T15:31:21Z The reaction of Salen-like Zn<sup>II </sup>and Ni<sup>II</sup> precursors with carbacylamidophosphate lanthanide moieties yields six new types of 3d–4f compounds. The complexes were characterized by means of <sup>1</sup>H, <sup>31</sup>P NMR and IR spectroscopy, elemental analysis, ESI mass spectrometry, and X-ray diffraction analysis. Depending on the Schiff base ligands, the Ni<sup>II</sup> ion adopts either a square-planar or an octahedral geometry, whereas the Zn<sup>II</sup> ion has a tetragonal-pyramidal geometry. The coordination number of lanthanides is nine or ten. Hydrolytic activities of some heterobimetallic Zn–Ln and Ni–Ln coordination compounds in the reaction of intramolecular hydrolytic degradation of the 2-(hydroxypropyl)-p-nitrophenyl phosphate were investigated. Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity Shishkin, Oleg V.

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