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Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations

Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations

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BABUSHKIN, Dmitrii E., Valentina N. PANCHENKO, Hans-Herbert BRINTZINGER, 2014. Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations. In: Angewandte Chemie International Edition. 53(36), pp. 9645-9649. ISSN 0570-0833. eISSN 1521-3773

@article{Babushkin2014Zirco-29332, title={Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations}, year={2014}, doi={10.1002/anie.201403673}, number={36}, volume={53}, issn={0570-0833}, journal={Angewandte Chemie International Edition}, pages={9645--9649}, author={Babushkin, Dmitrii E. and Panchenko, Valentina N. and Brintzinger, Hans-Herbert} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/29332"> <dc:contributor>Babushkin, Dmitrii E.</dc:contributor> <dcterms:abstract xml:lang="eng">In a search for the hitherto elusive catalyst resting state(s) of zirconocene-based olefin polymerization catalysts, a combination of UV/Vis and NMR spectrometric methods reveals that polymer-carrying cationic Zr allyl complexes make up about 90 % of the total catalyst concentration. Other catalyst species that take part in the polymerization process have to be generated from this allyl pool into which they appear to relapse rather frequently.</dcterms:abstract> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/29332"/> <dc:creator>Brintzinger, Hans-Herbert</dc:creator> <dc:contributor>Panchenko, Valentina N.</dc:contributor> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-11-27T10:15:59Z</dc:date> <dcterms:issued>2014</dcterms:issued> <dc:language>eng</dc:language> <dc:creator>Panchenko, Valentina N.</dc:creator> <dc:creator>Babushkin, Dmitrii E.</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-11-27T10:15:59Z</dcterms:available> <dcterms:title>Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations</dcterms:title> <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor> </rdf:Description> </rdf:RDF>

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