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Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems

Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems

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KOWALSKI, Konrad, Lukasz SZCZUPAK, Joanna SKIBA, Obadah S. ABDEL-RAHMAN, Rainer F. WINTER, Rafal CZERWIENIEC, Bruno THERRIEN, 2014. Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems. In: Organometallics. 33(18), pp. 4697-4705. ISSN 0276-7333. eISSN 1520-6041

@article{Kowalski2014Synth-29102, title={Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems}, year={2014}, doi={10.1021/om401191q}, number={18}, volume={33}, issn={0276-7333}, journal={Organometallics}, pages={4697--4705}, author={Kowalski, Konrad and Szczupak, Lukasz and Skiba, Joanna and Abdel-Rahman, Obadah S. and Winter, Rainer F. and Czerwieniec, Rafal and Therrien, Bruno} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/29102"> <dc:creator>Abdel-Rahman, Obadah S.</dc:creator> <dc:contributor>Skiba, Joanna</dc:contributor> <dc:creator>Winter, Rainer F.</dc:creator> <dc:creator>Skiba, Joanna</dc:creator> <dcterms:abstract xml:lang="eng">The synthesis of two new donor–acceptor ferrocenyl derivatives with Meldrum’s acid based nonplanar acceptor substituents is presented. Both compounds are obtained in high yields in a simple reaction protocol under mild conditions using either 1-acetyl- or 1,1′-diacetylferrocene and Meldrum’s acid. Both products have been characterized spectroscopically, by single-crystal X-ray structure analysis, by electrochemical and UV/vis/IR spectroelectrochemical measurements, and by (TD)-DFT calculations. The spectroelectrochemical measurements disclose that the 2,2-dimethyl-1,3-dioxane-4,6-dione moiety is a moderately strong electron acceptor.</dcterms:abstract> <dc:contributor>Szczupak, Lukasz</dc:contributor> <dc:creator>Czerwieniec, Rafal</dc:creator> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-10-13T08:45:27Z</dc:date> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-10-13T08:45:27Z</dcterms:available> <dc:language>eng</dc:language> <dc:creator>Therrien, Bruno</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/29102"/> <dc:contributor>Therrien, Bruno</dc:contributor> <dc:contributor>Abdel-Rahman, Obadah S.</dc:contributor> <dc:creator>Szczupak, Lukasz</dc:creator> <dc:contributor>Kowalski, Konrad</dc:contributor> <dc:creator>Kowalski, Konrad</dc:creator> <dc:contributor>Czerwieniec, Rafal</dc:contributor> <dcterms:issued>2014</dcterms:issued> <dcterms:title>Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems</dcterms:title> <dc:contributor>Winter, Rainer F.</dc:contributor> </rdf:Description> </rdf:RDF>

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