KOPS - The Institutional Repository of the University of Konstanz

Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems

Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems

Cite This

Files in this item

Files Size Format View

There are no files associated with this item.

KOWALSKI, Konrad, Lukasz SZCZUPAK, Joanna SKIBA, Obadah S. ABDEL-RAHMAN, Rainer F. WINTER, Rafal CZERWIENIEC, Bruno THERRIEN, 2014. Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems. In: Organometallics. 33(18), pp. 4697-4705. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om401191q

@article{Kowalski2014Synth-29102, title={Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems}, year={2014}, doi={10.1021/om401191q}, number={18}, volume={33}, issn={0276-7333}, journal={Organometallics}, pages={4697--4705}, author={Kowalski, Konrad and Szczupak, Lukasz and Skiba, Joanna and Abdel-Rahman, Obadah S. and Winter, Rainer F. and Czerwieniec, Rafal and Therrien, Bruno} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/29102"> <dc:creator>Winter, Rainer F.</dc:creator> <dc:creator>Abdel-Rahman, Obadah S.</dc:creator> <dc:contributor>Skiba, Joanna</dc:contributor> <dc:creator>Skiba, Joanna</dc:creator> <dcterms:abstract xml:lang="eng">The synthesis of two new donor–acceptor ferrocenyl derivatives with Meldrum’s acid based nonplanar acceptor substituents is presented. Both compounds are obtained in high yields in a simple reaction protocol under mild conditions using either 1-acetyl- or 1,1′-diacetylferrocene and Meldrum’s acid. Both products have been characterized spectroscopically, by single-crystal X-ray structure analysis, by electrochemical and UV/vis/IR spectroelectrochemical measurements, and by (TD)-DFT calculations. The spectroelectrochemical measurements disclose that the 2,2-dimethyl-1,3-dioxane-4,6-dione moiety is a moderately strong electron acceptor.</dcterms:abstract> <dc:contributor>Szczupak, Lukasz</dc:contributor> <dc:creator>Czerwieniec, Rafal</dc:creator> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-10-13T08:45:27Z</dc:date> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-10-13T08:45:27Z</dcterms:available> <dc:language>eng</dc:language> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dc:creator>Therrien, Bruno</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/29102"/> <dc:creator>Szczupak, Lukasz</dc:creator> <dc:contributor>Therrien, Bruno</dc:contributor> <dc:contributor>Abdel-Rahman, Obadah S.</dc:contributor> <dc:contributor>Kowalski, Konrad</dc:contributor> <dc:creator>Kowalski, Konrad</dc:creator> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:contributor>Czerwieniec, Rafal</dc:contributor> <dcterms:title>Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems</dcterms:title> <dcterms:issued>2014</dcterms:issued> <dc:contributor>Winter, Rainer F.</dc:contributor> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> </rdf:Description> </rdf:RDF>

This item appears in the following Collection(s)

Search KOPS


Browse

My Account