KOPS - Das Institutionelle Repositorium der Universität Konstanz

Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization

Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization

Zitieren

Dateien zu dieser Ressource

Dateien Größe Format Anzeige

Zu diesem Dokument gibt es keine Dateien.

WUCHER, Philipp, Judith B. SCHWADERER, Stefan MECKING, 2014. Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization. In: ACS Catalysis. 4(8), pp. 2672-2679. ISSN 2155-5435. eISSN 2155-5435

@article{Wucher2014Solid-28481, title={Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization}, year={2014}, doi={10.1021/cs5005954}, number={8}, volume={4}, issn={2155-5435}, journal={ACS Catalysis}, pages={2672--2679}, author={Wucher, Philipp and Schwaderer, Judith B. and Mecking, Stefan} }

Mecking, Stefan Schwaderer, Judith B. eng Wucher, Philipp Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization 2014-07-21T08:01:56Z 2014 Wucher, Philipp Mecking, Stefan Schwaderer, Judith B. deposit-license ACS Catalysis ; 4 (2014). - S. 2672-2679 Heterogenized representatives of neutral phosphine sulfonato Pd(II) complexes for polar monomer insertion polymerization were prepared by two different approaches. [{κ<sup>2</sup>-(P,O)-(2-anisyl)<sub>2</sub>PC<sub>6</sub>H<sub>4</sub>SO<sub>2</sub>O}Pd(Me)L] (L = pyr, dmso, or Cl) complexes were physisorbed on inorganic substrates, namely, clay or silica. In addition, new phosphine sulfonato complexes bearing hydroxyl linker groups at the nonchelating P-aryl moiety were prepared. These complexes were covalently tethered to cross-linked polystyrene. All immobilized palladium complexes are active in ethylene polymerization and<br />ethylene/MA copolymerization without any additional cocatalyst. In addition, separation from the polymer solution formed and reutilization for another polymerization were demonstrated for polystyrene-bound complexes. 2014-07-21T08:01:56Z

Das Dokument erscheint in:

KOPS Suche


Stöbern

Mein Benutzerkonto