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Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization

Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization

Publikationstyp: Zeitschriftenartikel
Autor/innen: Wucher, Philipp; Schwaderer, Judith B.; Mecking, Stefan
Erscheinungsjahr: 2014
Erschienen in: ACS Catalysis ; 4 (2014), 8. - S. 2672-2679. - ISSN 2155-5435. - eISSN 2155-5435
DOI (zitierfähiger Link): https://dx.doi.org/10.1021/cs5005954
Zusammenfassung:
Heterogenized representatives of neutral phosphine sulfonato Pd(II) complexes for polar monomer insertion polymerization were prepared by two different approaches. [{κ2-(P,O)-(2-anisyl)2PC6H4SO2O}Pd(Me)L] (L = pyr, dmso, or Cl) complexes were physisorbed on inorganic substrates, namely, clay or silica. In addition, new phosphine sulfonato complexes bearing hydroxyl linker groups at the nonchelating P-aryl moiety were prepared. These complexes were covalently tethered to cross-linked polystyrene. All immobilized palladium complexes are active in ethylene polymerization and
ethylene/MA copolymerization without any additional cocatalyst. In addition, separation from the polymer solution formed and reutilization for another polymerization were demonstrated for polystyrene-bound complexes.
Fachgebiet (DDC): 540 Chemie
Schlagwörter: insertion polymerization, polar monomer, palladium, supported, silica, montmorillonite clay, polystyrene beads
Link zur Lizenz: Deposit-Lizenz
Universitätsbibliographie: Ja

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WUCHER, Philipp, Judith B. SCHWADERER, Stefan MECKING, 2014. Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization. In: ACS Catalysis. 4(8), pp. 2672-2679. ISSN 2155-5435. eISSN 2155-5435. Available under: doi: 10.1021/cs5005954

@article{Wucher2014Solid-28481, title={Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization}, year={2014}, doi={10.1021/cs5005954}, number={8}, volume={4}, issn={2155-5435}, journal={ACS Catalysis}, pages={2672--2679}, author={Wucher, Philipp and Schwaderer, Judith B. and Mecking, Stefan} }

Mecking, Stefan Schwaderer, Judith B. eng Wucher, Philipp Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization 2014-07-21T08:01:56Z 2014 Wucher, Philipp Mecking, Stefan Schwaderer, Judith B. deposit-license ACS Catalysis ; 4 (2014). - S. 2672-2679 Heterogenized representatives of neutral phosphine sulfonato Pd(II) complexes for polar monomer insertion polymerization were prepared by two different approaches. [{κ<sup>2</sup>-(P,O)-(2-anisyl)<sub>2</sub>PC<sub>6</sub>H<sub>4</sub>SO<sub>2</sub>O}Pd(Me)L] (L = pyr, dmso, or Cl) complexes were physisorbed on inorganic substrates, namely, clay or silica. In addition, new phosphine sulfonato complexes bearing hydroxyl linker groups at the nonchelating P-aryl moiety were prepared. These complexes were covalently tethered to cross-linked polystyrene. All immobilized palladium complexes are active in ethylene polymerization and<br />ethylene/MA copolymerization without any additional cocatalyst. In addition, separation from the polymer solution formed and reutilization for another polymerization were demonstrated for polystyrene-bound complexes. 2014-07-21T08:01:56Z

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