Saturated polar-substituted polyethylene elastomers from insertion polymerization

Rünzi, Thomas; Mecking, Stefan

Saturated polar-substituted polyethylene elastomers from insertion polymerization

Dateien

Ruenzi_270869.pdfGröße: 346.7 KBDownloads: 444

Datum

2014

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Advanced Functional Materials. 2014, 24(3), pp. 387-395. ISSN 1616-301X. eISSN 1616-3028. Available under: doi: 10.1002/adfm.201301755

Zusammenfassung

Saturated, polar-substituted elastomers consisting of a linear polyethylene backbone are prepared directly by insertion copolymerization of ethylene with polar-functionalized vinyl monomers employing functional-group tolerant catalysis. This unprecedented approach to elastomers is compatible with a wide range of different crosslinking chemistries. Crosslinking of the materials occurs efficiently, as concluded from gel contents and spectroscopic observations. Mechanical and thermal properties are revealed by dynamic mechanical analysis.

Fachgebiet (DDC)

540 Chemie

Schlagwörter

elastomers, crosslinking, insertion polymerization, dynamic mechanical analysis, catalysts

Zitieren

ISO 690

RÜNZI, Thomas, Stefan MECKING, 2014. Saturated polar-substituted polyethylene elastomers from insertion polymerization. In: Advanced Functional Materials. 2014, 24(3), pp. 387-395. ISSN 1616-301X. eISSN 1616-3028. Available under: doi: 10.1002/adfm.201301755

BibTex

@article{Runzi2014Satur-27086,
  year={2014},
  doi={10.1002/adfm.201301755},
  title={Saturated polar-substituted polyethylene elastomers from insertion polymerization},
  number={3},
  volume={24},
  issn={1616-301X},
  journal={Advanced Functional Materials},
  pages={387--395},
  author={Rünzi, Thomas and Mecking, Stefan}
}

RDF

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/27086">
    <dc:language>eng</dc:language>
    <dc:rights>terms-of-use</dc:rights>
    <dc:contributor>Rünzi, Thomas</dc:contributor>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-03-17T14:46:36Z</dc:date>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/27086"/>
    <dcterms:issued>2014</dcterms:issued>
    <dcterms:bibliographicCitation>Advanced Functional Materials ; 24 (2014), 3. - S. 387-395</dcterms:bibliographicCitation>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:abstract xml:lang="eng">Saturated, polar-substituted elastomers consisting of a linear polyethylene backbone are prepared directly by insertion copolymerization of ethylene with polar-functionalized vinyl monomers employing functional-group tolerant catalysis. This unprecedented approach to elastomers is compatible with a wide range of different crosslinking chemistries. Crosslinking of the materials occurs efficiently, as concluded from gel contents and spectroscopic observations. Mechanical and thermal properties are revealed by dynamic mechanical analysis.</dcterms:abstract>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:creator>Mecking, Stefan</dc:creator>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-03-17T14:46:36Z</dcterms:available>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/27086/2/Ruenzi_270869.pdf"/>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dcterms:title>Saturated polar-substituted polyethylene elastomers from insertion polymerization</dcterms:title>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/27086/2/Ruenzi_270869.pdf"/>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:creator>Rünzi, Thomas</dc:creator>
    <dc:contributor>Mecking, Stefan</dc:contributor>
  </rdf:Description>
</rdf:RDF>

Universitätsbibliographie

Ja