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A straightforward treatment of activity in aqueous CaCO3 solutions and the consequences for nucleation theory

A straightforward treatment of activity in aqueous CaCO3 solutions and the consequences for nucleation theory

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KELLERMEIER, Matthias, Andreas PICKER, Andreas KEMPTER, Helmut CÖLFEN, Denis GEBAUER, 2014. A straightforward treatment of activity in aqueous CaCO3 solutions and the consequences for nucleation theory. In: Advanced Materials. 26(5), pp. 752-757. ISSN 0935-9648. eISSN 1521-4095

@article{Kellermeier2014-02strai-26223, title={A straightforward treatment of activity in aqueous CaCO3 solutions and the consequences for nucleation theory}, year={2014}, doi={10.1002/adma.201303643}, number={5}, volume={26}, issn={0935-9648}, journal={Advanced Materials}, pages={752--757}, author={Kellermeier, Matthias and Picker, Andreas and Kempter, Andreas and Cölfen, Helmut and Gebauer, Denis} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/26223"> <dc:creator>Cölfen, Helmut</dc:creator> <dc:contributor>Gebauer, Denis</dc:contributor> <dc:contributor>Kempter, Andreas</dc:contributor> <dc:creator>Gebauer, Denis</dc:creator> <dcterms:issued>2014-02</dcterms:issued> <dc:language>eng</dc:language> <dcterms:bibliographicCitation>Advanced Materials ; 26 (2014), 5. - S. 752-757</dcterms:bibliographicCitation> <dc:contributor>Cölfen, Helmut</dc:contributor> <dcterms:abstract xml:lang="eng">The aqueous calcium carbonate system is rigorously investigated with respect to ionic activity. Ideal treatment is found to be a good approximation at relevant concentrations. The data further show that bound CaCO3 species cannot be regarded as "inactive" during nucleation but rather appear to play a key role in the phase-separation process, and that amorphous calcium carbonate (ACC) can be precipitated from much lower levels of supersaturation than previously believed.</dcterms:abstract> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/26223"/> <dc:creator>Picker, Andreas</dc:creator> <dc:creator>Kellermeier, Matthias</dc:creator> <dcterms:title>A straightforward treatment of activity in aqueous CaCO3 solutions and the consequences for nucleation theory</dcterms:title> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-02-05T10:48:05Z</dcterms:available> <dc:contributor>Kellermeier, Matthias</dc:contributor> <dc:creator>Kempter, Andreas</dc:creator> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-02-05T10:48:05Z</dc:date> <dc:contributor>Picker, Andreas</dc:contributor> <dc:rights>deposit-license</dc:rights> </rdf:Description> </rdf:RDF>

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