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Cooperative Catalysis in Glycosidation Reactions with O-Glycosyl Trichloroacetimidates as Glycosyl Donors

Cooperative Catalysis in Glycosidation Reactions with O-Glycosyl Trichloroacetimidates as Glycosyl Donors

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GENG, Yiqun, Amit KUMAR, Hassan M. FAIDALLAH, Hassan A. ALBAR, Ibrahim A. MHKALID, Richard SCHMIDT, 2013. Cooperative Catalysis in Glycosidation Reactions with O-Glycosyl Trichloroacetimidates as Glycosyl Donors. In: Angewandte Chemie International Edition. 52(38), pp. 10089-10092. ISSN 1433-7851. eISSN 1521-3773

@article{Geng2013-09-16Coope-26063, title={Cooperative Catalysis in Glycosidation Reactions with O-Glycosyl Trichloroacetimidates as Glycosyl Donors}, year={2013}, doi={10.1002/anie.201302158}, number={38}, volume={52}, issn={1433-7851}, journal={Angewandte Chemie International Edition}, pages={10089--10092}, author={Geng, Yiqun and Kumar, Amit and Faidallah, Hassan M. and Albar, Hassan A. and Mhkalid, Ibrahim A. and Schmidt, Richard} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/26063"> <dc:language>eng</dc:language> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-01-31T10:21:43Z</dcterms:available> <dc:creator>Faidallah, Hassan M.</dc:creator> <dc:rights>deposit-license</dc:rights> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-01-31T10:21:43Z</dc:date> <dc:creator>Kumar, Amit</dc:creator> <dcterms:title>Cooperative Catalysis in Glycosidation Reactions with O-Glycosyl Trichloroacetimidates as Glycosyl Donors</dcterms:title> <dc:creator>Mhkalid, Ibrahim A.</dc:creator> <dc:contributor>Kumar, Amit</dc:contributor> <dc:contributor>Geng, Yiqun</dc:contributor> <dc:creator>Schmidt, Richard</dc:creator> <dc:contributor>Albar, Hassan A.</dc:contributor> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dcterms:abstract xml:lang="eng">Thiourea mediates cooperative glycosidation through hydrogen bonding. N,N′-Diarylthiourea as cocatalyst enforces an SN2-type acid-catalyzed glycosidation even at room temperature (see scheme; Bn=benzyl). From O-(α-glycosyl) trichloroacetimidates as glycosyl donors and various acceptors, β-glycosides are preferentially or exclusively obtained.</dcterms:abstract> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/26063"/> <dcterms:bibliographicCitation>Angewandte Chemie International Edition ; 52 (2013), 38. - S. 10089-10092</dcterms:bibliographicCitation> <dc:creator>Geng, Yiqun</dc:creator> <dc:contributor>Faidallah, Hassan M.</dc:contributor> <dcterms:issued>2013-09-16</dcterms:issued> <dc:contributor>Mhkalid, Ibrahim A.</dc:contributor> <dc:contributor>Schmidt, Richard</dc:contributor> <dc:creator>Albar, Hassan A.</dc:creator> </rdf:Description> </rdf:RDF>

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