Ralfuranone Thioether Production by the Plant Pathogen Ralstonia solanacearum

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PAULY, Julia, Dieter SPITELLER, Jeanine LINZ, Jonathan JACOBS, Caitilyn ALLEN, Markus NETT, Dirk HOFFMEISTER, 2013. Ralfuranone Thioether Production by the Plant Pathogen Ralstonia solanacearum. In: ChemBioChem. 14(16), pp. 2169-2178. ISSN 1439-4227. eISSN 1439-7633

@article{Pauly2013-11-04Ralfu-25172, title={Ralfuranone Thioether Production by the Plant Pathogen Ralstonia solanacearum}, year={2013}, doi={10.1002/cbic.201300364}, number={16}, volume={14}, issn={1439-4227}, journal={ChemBioChem}, pages={2169--2178}, author={Pauly, Julia and Spiteller, Dieter and Linz, Jeanine and Jacobs, Jonathan and Allen, Caitilyn and Nett, Markus and Hoffmeister, Dirk} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/25172"> <dc:creator>Hoffmeister, Dirk</dc:creator> <dc:creator>Linz, Jeanine</dc:creator> <dc:rights>deposit-license</dc:rights> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dc:contributor>Nett, Markus</dc:contributor> <dc:contributor>Hoffmeister, Dirk</dc:contributor> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-11-22T10:00:54Z</dc:date> <dc:creator>Jacobs, Jonathan</dc:creator> <dcterms:title>Ralfuranone Thioether Production by the Plant Pathogen Ralstonia solanacearum</dcterms:title> <dc:creator>Nett, Markus</dc:creator> <dc:creator>Pauly, Julia</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/25172"/> <dcterms:bibliographicCitation>ChemBioChem ; 14 (2013), 16. - S. 2169–2178</dcterms:bibliographicCitation> <dc:creator>Allen, Caitilyn</dc:creator> <dcterms:abstract xml:lang="eng">Ralfuranones are aryl-substituted furanone secondary metabolites of the Gram-negative plant pathogen Ralstonia solanacearum. New sulfur-containing ralfuranone derivatives were identified, including the methyl thioether-containing ralfuranone D. Isotopic labeling in vivo, as well as headspace analyses of volatiles from R. solanacearum liquid cultures, established a mechanism for the transfer of an intact methylthio group from L-methionine or α-keto-γ-methylthiobutyric acid. The methylthio acceptor molecule ralfuranone I, a previously postulated biosynthetic intermediate in ralfuranone biosynthesis, was isolated and characterized by NMR. The highly reactive Michael acceptor system of this intermediate readily reacts with various thiols, including glutathione.</dcterms:abstract> <dcterms:issued>2013-11-04</dcterms:issued> <dc:contributor>Pauly, Julia</dc:contributor> <dc:contributor>Linz, Jeanine</dc:contributor> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-11-22T10:00:54Z</dcterms:available> <dc:contributor>Spiteller, Dieter</dc:contributor> <dc:language>eng</dc:language> <dc:creator>Spiteller, Dieter</dc:creator> <dc:contributor>Jacobs, Jonathan</dc:contributor> <dc:contributor>Allen, Caitilyn</dc:contributor> </rdf:Description> </rdf:RDF>

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