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Assignment of the NV<sup>0 </sup>575-nm zero-phonon line in diamond to a <sup>2</sup>E-<sup>2</sup>A<sub>2</sub> transition

Assignment of the NV0 575-nm zero-phonon line in diamond to a 2E-2A2 transition

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MANSON, Neil B., Katja BEHA, Anton BATALOV, Lachlan J. ROGERS, Marcus W. DOHERTY, Rudolf BRATSCHITSCH, Alfred LEITENSTORFER, 2013. Assignment of the NV0 575-nm zero-phonon line in diamond to a 2E-2A2 transition. In: Physical Review B. 87(15). ISSN 1098-0121

@article{Manson2013Assig-24474, title={Assignment of the NV0 575-nm zero-phonon line in diamond to a 2E-2A2 transition}, year={2013}, doi={10.1103/PhysRevB.87.155209}, number={15}, volume={87}, issn={1098-0121}, journal={Physical Review B}, author={Manson, Neil B. and Beha, Katja and Batalov, Anton and Rogers, Lachlan J. and Doherty, Marcus W. and Bratschitsch, Rudolf and Leitenstorfer, Alfred} }

Leitenstorfer, Alfred Manson, Neil B. The time-averaged emission spectrum of single nitrogen-vacancy defects in diamond gives zero-phonon lines of both the negative charge state at 637 nm (1.945 eV) and the neutral charge state at 575 nm (2.156 eV). This occurs through photoconversion cycling between the two charge states. Due to strain in the diamond the zero-phonon lines of both charge states are split and it is found that the splitting and polarization of the two zero-phonon lines are the same. From this observation and consideration of the electronic structure of the nitrogen-vacancy center it is concluded that the excited state of the neutral center has A<sub>2</sub> orbital symmetry. The assignment of the 575-nm transition to a <sup>2</sup>E-<sup>2</sup>A<sub>2</sub> transition has not been established previously. Doherty, Marcus W. Manson, Neil B. 2013-09-30T12:09:44Z Batalov, Anton Batalov, Anton Physical Review B ; 87 (2013), 15. - Art. 155209 [5 Seiten] 2013-09-30T12:09:44Z Bratschitsch, Rudolf Doherty, Marcus W. Leitenstorfer, Alfred 2013 deposit-license Assignment of the NV<sup>0 </sup>575-nm zero-phonon line in diamond to a <sup>2</sup>E-<sup>2</sup>A<sub>2</sub> transition Bratschitsch, Rudolf eng Rogers, Lachlan J. Rogers, Lachlan J. Beha, Katja Beha, Katja

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