Ligand Mobility in Carbyne Complexes


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FISCHER, Helmut, Andreas MOTSCH, Ulrich SCHUBERT, Dietmar NEUGEBAUER, 1981. Ligand Mobility in Carbyne Complexes. In: Angewandte Chemie International Edition in English. 20(5), pp. 463-464. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.198104631

@article{Fischer1981Ligan-24261, title={Ligand Mobility in Carbyne Complexes}, year={1981}, doi={10.1002/anie.198104631}, number={5}, volume={20}, issn={0570-0833}, journal={Angewandte Chemie International Edition in English}, pages={463--464}, author={Fischer, Helmut and Motsch, Andreas and Schubert, Ulrich and Neugebauer, Dietmar} }

Angewandte Chemie International Edition ; 20 (1981), 5. - S. 463-464 2013-08-09T11:45:50Z 2013-08-09T11:45:50Z Neugebauer, Dietmar Schubert, Ulrich Unusual reactions of carbyne complexes have been observed with the octahedrally coordinated compounds (1) to (3). Thus reaction of (1) with NR<sub>4</sub>X (X = halogen) leads, via isomerization, to the neutral complex (2). The complex (2) is similarly obtained in an equilibrium reaction from (3) and PPh<sub>3</sub>. Motsch, Andreas Fischer, Helmut Fischer, Helmut eng terms-of-use Motsch, Andreas Schubert, Ulrich Ligand Mobility in Carbyne Complexes Neugebauer, Dietmar 1981

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