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Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents

Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents

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FORSYTH, John, José M. PEREÑA, Rosario BENAVENTE, Ernesto PÉREZ, Incoronata TRITTO, Laura BOGGIONI, Hans-Herbert BRINTZINGER, 2001. Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents. In: Macromolecular Chemistry and Physics. 202(5), pp. 614-620. ISSN 1022-1352. eISSN 1521-3935. Available under: doi: 10.1002/1521-3935(20010301)202:5<614::AID-MACP614>3.0.CO;2-C

@article{Forsyth2001Influ-24064, title={Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents}, year={2001}, doi={10.1002/1521-3935(20010301)202:5<614::AID-MACP614>3.0.CO;2-C}, number={5}, volume={202}, issn={1022-1352}, journal={Macromolecular Chemistry and Physics}, pages={614--620}, author={Forsyth, John and Pereña, José M. and Benavente, Rosario and Pérez, Ernesto and Tritto, Incoronata and Boggioni, Laura and Brintzinger, Hans-Herbert} }

terms-of-use Forsyth, John This study involves research on possible relationships between the composition of ethylene/norbornene copolymers and their thermal properties. The copolymers were fully characterised by differential scanning calorimetry (DSC), <sup>13</sup>C NMR spectroscopy, Fourier transformation infra-red (FTIR) and Raman spectroscopy. The results of this study show that there is no linear correlation between the amount of norbornene incorporated in copolymers and thermal behaviour when copolymers containing high norbornene content and different microstructures are considered. The latter of which was found to be extremely sensitive to the catalyst used in its preparation. Benavente, Rosario Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents Tritto, Incoronata Pérez, Ernesto 2013-09-05T12:22:01Z Pérez, Ernesto Benavente, Rosario Pereña, José M. Macromolecular Chemistry and Physics ; 202 (2001), 5. - S. 614-620 2013-09-05T12:22:01Z eng Boggioni, Laura Forsyth, John Pereña, José M. 2001 Tritto, Incoronata Brintzinger, Hans-Herbert Boggioni, Laura Brintzinger, Hans-Herbert

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