ansa-metallocene derivatives : XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands

Thumbnail Image
Date
1987
Authors
Zsolnai, Laszlo
Huttner, Gottfried
Editors
Contact
Journal ISSN
Electronic ISSN
ISBN
Bibliographical data
Publisher
Series
URI (citable link)
ArXiv-ID
International patent number
Link to the license
EU project number
Project
Open Access publication
Collections
Restricted until
Title in another language
Research Projects
Organizational Units
Journal Issue
Publication type
Journal article
Publication status
Published in
Journal of Organometallic Chemistry ; 322 (1987), 1. - pp. 65-70. - ISSN 0022-328X
Abstract
The chiral ansa-titanocene derivative 1,3-propanediylbis(4,5,6,7-tetrahydro-1-indenyl)titanium(IV) dichloride has been prepared by reaction of the dilithium salt of 1,3-bis(indenyl)propane with TiCl4 and subsequent hydrogenation. The product has been shown by an X-ray diffraction study to be the R,S metal-ring linkage isomer; in this trimethylene-bridged ansa-metallocene the axial symmetry previously observed for te ethylene-bridged congener is destroyed by a non-symmetric location of the (CH2)3 bridge.
Summary in another language
Subject (DDC)
540 Chemistry
Keywords
Conference
Review
undefined / . - undefined, undefined. - (undefined; undefined)
Cite This
ISO 690RÖLL, Werner, Laszlo ZSOLNAI, Gottfried HUTTNER, Hans-Herbert BRINTZINGER, 1987. ansa-metallocene derivatives : XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands. In: Journal of Organometallic Chemistry. 322(1), pp. 65-70. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(87)85024-6
BibTex
@article{Roll1987ansam-24054,
  year={1987},
  doi={10.1016/0022-328X(87)85024-6},
  title={ansa-metallocene derivatives : XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands},
  number={1},
  volume={322},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={65--70},
  author={Röll, Werner and Zsolnai, Laszlo and Huttner, Gottfried and Brintzinger, Hans-Herbert}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/24054">
    <dc:contributor>Huttner, Gottfried</dc:contributor>
    <dc:creator>Brintzinger, Hans-Herbert</dc:creator>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/24054"/>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/24054/2/Roell_240547.pdf"/>
    <dc:contributor>Röll, Werner</dc:contributor>
    <dcterms:abstract xml:lang="eng">The chiral ansa-titanocene derivative 1,3-propanediylbis(4,5,6,7-tetrahydro-1-indenyl)titanium(IV) dichloride has been prepared by reaction of the dilithium salt of 1,3-bis(indenyl)propane with TiCl&lt;sub&gt;4&lt;/sub&gt; and subsequent hydrogenation. The product has been shown by an X-ray diffraction study to be the R,S metal-ring linkage isomer; in this trimethylene-bridged ansa-metallocene the axial symmetry previously observed for te ethylene-bridged congener is destroyed by a non-symmetric location of the (CH&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt; bridge.</dcterms:abstract>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-07-11T09:10:38Z</dcterms:available>
    <dcterms:title>ansa-metallocene derivatives : XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands</dcterms:title>
    <dc:contributor>Zsolnai, Laszlo</dc:contributor>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/24054/2/Roell_240547.pdf"/>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:creator>Röll, Werner</dc:creator>
    <dcterms:bibliographicCitation>Journal of Organometallic Chemistry ; 322 (1987), 1. - S. 65-70</dcterms:bibliographicCitation>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:rights>terms-of-use</dc:rights>
    <dc:creator>Zsolnai, Laszlo</dc:creator>
    <dcterms:issued>1987</dcterms:issued>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:language>eng</dc:language>
    <dc:creator>Huttner, Gottfried</dc:creator>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-07-11T09:10:38Z</dc:date>
  </rdf:Description>
</rdf:RDF>
Internal note
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Contact
URL of original publication
Test date of URL
Examination date of dissertation
Method of financing
Comment on publication
Alliance license
Corresponding Authors der Uni Konstanz vorhanden
International Co-Authors
Bibliography of Konstanz
No
Refereed