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ansa-metallocene derivatives : XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands

ansa-metallocene derivatives : XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands

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Prüfsumme: MD5:4c0b2ea40fadb584bd66e1dd74d5797d

RÖLL, Werner, Laszlo ZSOLNAI, Gottfried HUTTNER, Hans-Herbert BRINTZINGER, 1987. ansa-metallocene derivatives : XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands. In: Journal of Organometallic Chemistry. 322(1), pp. 65-70. ISSN 0022-328X

@article{Roll1987ansa--24054, title={ansa-metallocene derivatives : XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands}, year={1987}, doi={10.1016/0022-328X(87)85024-6}, number={1}, volume={322}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={65--70}, author={Röll, Werner and Zsolnai, Laszlo and Huttner, Gottfried and Brintzinger, Hans-Herbert} }

Röll, Werner Brintzinger, Hans-Herbert ansa-metallocene derivatives : XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands Röll, Werner 1987 Zsolnai, Laszlo Huttner, Gottfried 2013-07-11T09:10:38Z Zsolnai, Laszlo The chiral ansa-titanocene derivative 1,3-propanediylbis(4,5,6,7-tetrahydro-1-indenyl)titanium(IV) dichloride has been prepared by reaction of the dilithium salt of 1,3-bis(indenyl)propane with TiCl<sub>4</sub> and subsequent hydrogenation. The product has been shown by an X-ray diffraction study to be the R,S metal-ring linkage isomer; in this trimethylene-bridged ansa-metallocene the axial symmetry previously observed for te ethylene-bridged congener is destroyed by a non-symmetric location of the (CH<sub>2</sub>)<sub>3</sub> bridge. deposit-license 2013-07-11T09:10:38Z Brintzinger, Hans-Herbert Journal of Organometallic Chemistry ; 322 (1987), 1. - S. 65-70 eng Huttner, Gottfried

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