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ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands

ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands

Type of Publication: Journal article
URI (citable link): http://nbn-resolving.de/urn:nbn:de:bsz:352-239939
Author: Wild, Ferdinand R. W. P.; Wasiucionek, Marek; Huttner, Gottfried; Brintzinger, Hans-Herbert
Year of publication: 1985
Published in: Journal of Organometallic Chemistry ; 288 (1985), 1. - pp. 63-67. - ISSN 0022-328X
DOI (citable link): https://dx.doi.org/10.1016/0022-328X(85)80104-2
Summary:
The chiral ansa-zirconocene derivative ethylenebis(4,5,6,7-tetrahydro-1-indenyl)-zirconium(IV) dichloride has been prepared by reaction of dilithiobis(indenyl)ethane with ZrCl4 and subsequent hydrogenation. The product has been shown to be the 1-R,S rather than meso-metal-ring linkage stereoisomer by an X-ray determination of the molecular structure.
Subject (DDC): 540 Chemistry
Link to License: Terms of use

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WILD, Ferdinand R. W. P., Marek WASIUCIONEK, Gottfried HUTTNER, Hans-Herbert BRINTZINGER, 1985. ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands. In: Journal of Organometallic Chemistry. 288(1), pp. 63-67. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(85)80104-2

@article{Wild1985ansam-23993, title={ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands}, year={1985}, doi={10.1016/0022-328X(85)80104-2}, number={1}, volume={288}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={63--67}, author={Wild, Ferdinand R. W. P. and Wasiucionek, Marek and Huttner, Gottfried and Brintzinger, Hans-Herbert} }

eng 2013-07-09T13:20:26Z Wild, Ferdinand R. W. P. Wasiucionek, Marek ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands Wild, Ferdinand R. W. P. Journal of Organometallic Chemistry ; 288 (1985), 1. - S. 63-67 Brintzinger, Hans-Herbert The chiral ansa-zirconocene derivative ethylenebis(4,5,6,7-tetrahydro-1-indenyl)-zirconium(IV) dichloride has been prepared by reaction of dilithiobis(indenyl)ethane with ZrCl<sub>4</sub> and subsequent hydrogenation. The product has been shown to be the 1-R,S rather than meso-metal-ring linkage stereoisomer by an X-ray determination of the molecular structure. terms-of-use 2013-07-09T13:20:26Z 1985 Brintzinger, Hans-Herbert Huttner, Gottfried Huttner, Gottfried Wasiucionek, Marek

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