Benzene complexes in cyclopentadienylcobalt(I) reaction systems

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LEE, Wai-Sun, Johnson D. KOOLA, Hans-Herbert BRINTZINGER, 1981. Benzene complexes in cyclopentadienylcobalt(I) reaction systems. In: Journal of Organometallic Chemistry. 206(1), pp. C4-C6. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)93472-7

@article{Lee1981Benze-23957, title={Benzene complexes in cyclopentadienylcobalt(I) reaction systems}, year={1981}, doi={10.1016/S0022-328X(00)93472-7}, number={1}, volume={206}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={C4--C6}, author={Lee, Wai-Sun and Koola, Johnson D. and Brintzinger, Hans-Herbert} }

eng Brintzinger, Hans-Herbert Koola, Johnson D. Koola, Johnson D. Brintzinger, Hans-Herbert Photolysis of (C<sub>5</sub>H<sub>5</sub>)Co(CO)<sub>2</sub> in an aromatic solvent, such as benzene, toluene or s-mesitylene generates the corresponding (C<sub>5</sub>H<sub>5</sub>)Co(arene) and (C<sub>5</sub>H<sub>5</sub>)Co(arene)<sub>2</sub> complexes. The benzene complex (C<sub>5</sub>H<sub>5</sub>)Co(C<sub>6</sub>H<sub>6</sub>) reacts with 2-butyne to form the hexamethyl benzene derivative (C<sub>5</sub>H<sub>5</sub>)Co(C<sub>6</sub>(CH<sub>3</sub>)<sub>6</sub>) but does not catalyze the formation of free hexamethylbenzene from excess 2-butyne. 2013-07-26T10:21:58Z Benzene complexes in cyclopentadienylcobalt(I) reaction systems Lee, Wai-Sun 1981 Lee, Wai-Sun 2013-07-26T10:21:58Z Journal of Organometallic Chemistry ; 206 (1981), 1. - S. C4-C6 terms-of-use

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