Type of Publication: | Journal article |
URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-239516 |
Author: | Burger, Peter; Hund, Hans-Ulrich; Evertz, Kaspar; Brintzinger, Hans-Herbert |
Year of publication: | 1989 |
Published in: | Journal of Organometallic Chemistry ; 378 (1989), 2. - pp. 153-161. - ISSN 0022-328X |
DOI (citable link): | https://dx.doi.org/10.1016/0022-328X(89)80004-X |
Summary: |
The product of an Mg/CCl4-induced reductive coupling of guaiazulene reacts with TiCl3·3THF to yield, after oxidation with HCl/O2, R,S-8,8′-biguaiazulenide titanium dichloride, which contains a CC bond between its two guaiazulenide ligand moieties. A similar reaction sequence starting from 3-phenyl-1,2-dihydropentalene gives unbridged R,S-bis(4-exo-phenyl-4H-5,6-dihydropentalenide)titanium dichloride.
|
Subject (DDC): | 540 Chemistry |
Link to License: | In Copyright |
BURGER, Peter, Hans-Ulrich HUND, Kaspar EVERTZ, Hans-Herbert BRINTZINGER, 1989. ansa-metallocene derivatives : XVIII. Chiral titanocene derivatives accessible from substituted dihydropentalene and azulene precursors. In: Journal of Organometallic Chemistry. 378(2), pp. 153-161. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(89)80004-X
@article{Burger1989ansam-23951, title={ansa-metallocene derivatives : XVIII. Chiral titanocene derivatives accessible from substituted dihydropentalene and azulene precursors}, year={1989}, doi={10.1016/0022-328X(89)80004-X}, number={2}, volume={378}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={153--161}, author={Burger, Peter and Hund, Hans-Ulrich and Evertz, Kaspar and Brintzinger, Hans-Herbert} }
Burger_239516.pdf | 1183 |