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Ketene acetal metallocene complexes : Crystal structure of (C 5 H 5) 2 Ti(Cl)OC(OCH 3)=C(CH 3) 2

Ketene acetal metallocene complexes : Crystal structure of (C 5 H 5) 2 Ti(Cl)OC(OCH 3)=C(CH 3) 2

Type of Publication: Journal article
URI (citable link): http://nbn-resolving.de/urn:nbn:de:bsz:352-239338
Author: Hortmann, Kai; Diebold, Josef; Brintzinger, Hans-Herbert
Year of publication: 1993
Published in: Journal of Organometallic Chemistry ; 445 (1993), 1-2. - pp. 107-109. - ISSN 0022-328X. - eISSN 1872-8561
DOI (citable link): https://dx.doi.org/10.1016/0022-328X(93)80194-G
Summary:
Titanocene and zirconocene ketene acetal derivatives have been prepared by reaction of the respective metallocene dichloride with the lithium enolate of isobutyric acid methyl ester. The crystal structure of (C5H5)2Ti(Cl)OC(OCH3)=C(CH3) is reported.
Subject (DDC): 540 Chemistry
Link to License: Terms of use

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HORTMANN, Kai, Josef DIEBOLD, Hans-Herbert BRINTZINGER, 1993. Ketene acetal metallocene complexes : Crystal structure of (C 5 H 5) 2 Ti(Cl)OC(OCH 3)=C(CH 3) 2. In: Journal of Organometallic Chemistry. 445(1-2), pp. 107-109. ISSN 0022-328X. eISSN 1872-8561. Available under: doi: 10.1016/0022-328X(93)80194-G

@article{Hortmann1993Keten-23933, title={Ketene acetal metallocene complexes : Crystal structure of (C 5 H 5) 2 Ti(Cl)OC(OCH 3)=C(CH 3) 2}, year={1993}, doi={10.1016/0022-328X(93)80194-G}, number={1-2}, volume={445}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={107--109}, author={Hortmann, Kai and Diebold, Josef and Brintzinger, Hans-Herbert} }

Diebold, Josef Titanocene and zirconocene ketene acetal derivatives have been prepared by reaction of the respective metallocene dichloride with the lithium enolate of isobutyric acid methyl ester. The crystal structure of (C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>Ti(Cl)OC(OCH<sub>3</sub>)=C(CH<sub>3</sub>) is reported. Hortmann, Kai eng Journal of Organometallic Chemistry ; 445 (1993), 1-2. - S. 107-109 Brintzinger, Hans-Herbert Brintzinger, Hans-Herbert 1993 2013-08-02T12:36:03Z 2013-08-02T12:36:03Z terms-of-use Hortmann, Kai Diebold, Josef Ketene acetal metallocene complexes : Crystal structure of (C 5 H 5) 2 Ti(Cl)OC(OCH 3)=C(CH 3) 2

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