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Coordination of CO to the alkaline earth metallocene [(Me<sub>5</sub>C<sub>5</sub>)<sub>2</sub>Ca]

Coordination of CO to the alkaline earth metallocene [(Me5C5)2Ca]

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SELG, Peter, Hans-Herbert BRINTZINGER, Richard A. ANDERSEN, István T. HORVÁTH, 1995. Coordination of CO to the alkaline earth metallocene [(Me5C5)2Ca]. In: Angewandte Chemie International Edition in English. 34(7), pp. 791-793. ISSN 0570-0833. eISSN 1521-3773

@article{Selg1995Coord-23928, title={Coordination of CO to the alkaline earth metallocene [(Me5C5)2Ca]}, year={1995}, doi={10.1002/anie.199507911}, number={7}, volume={34}, issn={0570-0833}, journal={Angewandte Chemie International Edition in English}, pages={791--793}, author={Selg, Peter and Brintzinger, Hans-Herbert and Andersen, Richard A. and Horváth, István T.} }

Brintzinger, Hans-Herbert Horváth, István T. Andersen, Richard A. deposit-license 2013-08-08T06:33:26Z Selg, Peter Horváth, István T. Selg, Peter 2013-08-08T06:33:26Z The exothermic formation of a Ca–CO complex [Eq.(a), ΔHo = −25 kJ mol<sup>−1</sup>] confirms that CO can bind to a metal center without π back donation from filled d orbitals. In its spectroscopic properties, the calcocene–carbonyl complex resembles "nonclassical" noble metal carbonyl complexes. Cp* = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>. 1995 Andersen, Richard A. eng Coordination of CO to the alkaline earth metallocene [(Me<sub>5</sub>C<sub>5</sub>)<sub>2</sub>Ca] Brintzinger, Hans-Herbert Angewandte Chemie International Edition in English ; 34 (1995), 7. - S. 791-793

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