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The structure of (C<sub>5</sub>H<sub>5</sub>)<sub>2</sub> W(CO)<sub>2</sub> a compound containing a bent trihapto-cyclopentadienyl ligand

The structure of (C5H5)2 W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand

Publikationstyp: Zeitschriftenartikel
URI (zitierfähiger Link): http://nbn-resolving.de/urn:nbn:de:bsz:352-239138
Autor/innen: Huttner, Gottfried; Brintzinger, Hans-Herbert; Bell, Larry G.; Friedrich, Peter; Bejenke, Vera; Neugebauer, Dietmar
Erscheinungsjahr: 1978
Erschienen in: Journal of Organometallic Chemistry ; 145 (1978), 3. - S. 329-333. - ISSN 0022-328X
DOI (zitierfähiger Link): https://dx.doi.org/10.1016/S0022-328X(00)81301-7
Zusammenfassung:
The crystal and molecular structure of the complex (C5H5)2W(CO)2 has been determined by X-ray analysis R1 = 0.063). The structure contains a trihapto-cyclopentadienyl ligand, bent along its 1,3-axis by 20°. By this unusual structure, a 20-electron valence configuration of the central metal is avoided.
Fachgebiet (DDC): 540 Chemie
Link zur Lizenz: Deposit-Lizenz

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HUTTNER, Gottfried, Hans-Herbert BRINTZINGER, Larry G. BELL, Peter FRIEDRICH, Vera BEJENKE, Dietmar NEUGEBAUER, 1978. The structure of (C5H5)2 W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand. In: Journal of Organometallic Chemistry. 145(3), pp. 329-333. ISSN 0022-328X

@article{Huttner1978struc-23913, title={The structure of (C5H5)2 W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand}, year={1978}, doi={10.1016/S0022-328X(00)81301-7}, number={3}, volume={145}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={329--333}, author={Huttner, Gottfried and Brintzinger, Hans-Herbert and Bell, Larry G. and Friedrich, Peter and Bejenke, Vera and Neugebauer, Dietmar} }

1978 eng Bejenke, Vera Brintzinger, Hans-Herbert Bell, Larry G. Bell, Larry G. Neugebauer, Dietmar 2013-07-31T07:49:46Z Huttner, Gottfried Friedrich, Peter The structure of (C<sub>5</sub>H<sub>5</sub>)<sub>2</sub> W(CO)<sub>2</sub> a compound containing a bent trihapto-cyclopentadienyl ligand Huttner, Gottfried The crystal and molecular structure of the complex (C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>W(CO)<sub>2</sub> has been determined by X-ray analysis R<sub>1</sub> = 0.063). The structure contains a trihapto-cyclopentadienyl ligand, bent along its 1,3-axis by 20°. By this unusual structure, a 20-electron valence configuration of the central metal is avoided. Journal of Organometallic Chemistry ; 145 (1978), 3. - S. 329-333 Brintzinger, Hans-Herbert Neugebauer, Dietmar Friedrich, Peter 2013-07-31T07:49:46Z Bejenke, Vera deposit-license

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