Type of Publication: | Journal article |
URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-239138 |
Author: | Huttner, Gottfried; Brintzinger, Hans-Herbert; Bell, Larry G.; Friedrich, Peter; Bejenke, Vera; Neugebauer, Dietmar |
Year of publication: | 1978 |
Published in: | Journal of Organometallic Chemistry ; 145 (1978), 3. - pp. 329-333. - ISSN 0022-328X |
DOI (citable link): | https://dx.doi.org/10.1016/S0022-328X(00)81301-7 |
Summary: |
The crystal and molecular structure of the complex (C5H5)2W(CO)2 has been determined by X-ray analysis R1 = 0.063). The structure contains a trihapto-cyclopentadienyl ligand, bent along its 1,3-axis by 20°. By this unusual structure, a 20-electron valence configuration of the central metal is avoided.
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Subject (DDC): | 540 Chemistry |
Link to License: | In Copyright |
HUTTNER, Gottfried, Hans-Herbert BRINTZINGER, Larry G. BELL, Peter FRIEDRICH, Vera BEJENKE, Dietmar NEUGEBAUER, 1978. The structure of (C5H5)2 W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand. In: Journal of Organometallic Chemistry. 145(3), pp. 329-333. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)81301-7
@article{Huttner1978struc-23913, title={The structure of (C5H5)2 W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand}, year={1978}, doi={10.1016/S0022-328X(00)81301-7}, number={3}, volume={145}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={329--333}, author={Huttner, Gottfried and Brintzinger, Hans-Herbert and Bell, Larry G. and Friedrich, Peter and Bejenke, Vera and Neugebauer, Dietmar} }
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