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The structure of (C<sub>5</sub>H<sub>5</sub>)<sub>2</sub> W(CO)<sub>2</sub> a compound containing a bent trihapto-cyclopentadienyl ligand

The structure of (C5H5)2 W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand

Type of Publication: Journal article
URI (citable link): http://nbn-resolving.de/urn:nbn:de:bsz:352-239138
Author: Huttner, Gottfried; Brintzinger, Hans-Herbert; Bell, Larry G.; Friedrich, Peter; Bejenke, Vera; Neugebauer, Dietmar
Year of publication: 1978
Published in: Journal of Organometallic Chemistry ; 145 (1978), 3. - pp. 329-333. - ISSN 0022-328X
DOI (citable link): https://dx.doi.org/10.1016/S0022-328X(00)81301-7
Summary:
The crystal and molecular structure of the complex (C5H5)2W(CO)2 has been determined by X-ray analysis R1 = 0.063). The structure contains a trihapto-cyclopentadienyl ligand, bent along its 1,3-axis by 20°. By this unusual structure, a 20-electron valence configuration of the central metal is avoided.
Subject (DDC): 540 Chemistry
Link to License: In Copyright

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HUTTNER, Gottfried, Hans-Herbert BRINTZINGER, Larry G. BELL, Peter FRIEDRICH, Vera BEJENKE, Dietmar NEUGEBAUER, 1978. The structure of (C5H5)2 W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand. In: Journal of Organometallic Chemistry. 145(3), pp. 329-333. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)81301-7

@article{Huttner1978struc-23913, title={The structure of (C5H5)2 W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand}, year={1978}, doi={10.1016/S0022-328X(00)81301-7}, number={3}, volume={145}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={329--333}, author={Huttner, Gottfried and Brintzinger, Hans-Herbert and Bell, Larry G. and Friedrich, Peter and Bejenke, Vera and Neugebauer, Dietmar} }

eng 1978 Bejenke, Vera Brintzinger, Hans-Herbert Bell, Larry G. Bell, Larry G. Neugebauer, Dietmar Friedrich, Peter Huttner, Gottfried 2013-07-31T07:49:46Z The structure of (C<sub>5</sub>H<sub>5</sub>)<sub>2</sub> W(CO)<sub>2</sub> a compound containing a bent trihapto-cyclopentadienyl ligand Huttner, Gottfried The crystal and molecular structure of the complex (C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>W(CO)<sub>2</sub> has been determined by X-ray analysis R<sub>1</sub> = 0.063). The structure contains a trihapto-cyclopentadienyl ligand, bent along its 1,3-axis by 20°. By this unusual structure, a 20-electron valence configuration of the central metal is avoided. Journal of Organometallic Chemistry ; 145 (1978), 3. - S. 329-333 Brintzinger, Hans-Herbert Friedrich, Peter Neugebauer, Dietmar 2013-07-31T07:49:46Z terms-of-use Bejenke, Vera

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