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ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation

ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation

Type of Publication: Journal article
URI (citable link): http://nbn-resolving.de/urn:nbn:de:bsz:352-238908
Author: Huttenloch, Monika E.; Dorer, Birgit; Rief, Ursula; Prosenc, Marc-Heinrich; Schmidt, Katrin; Brintzinger, Hans-Herbert
Year of publication: 1997
Published in: Journal of Organometallic Chemistry ; 541 (1997), 1-2. - pp. 219-232. - ISSN 0022-328X
DOI (citable link): https://dx.doi.org/10.1016/S0022-328X(97)00064-8
Summary:
Chiral, biphenyl-bridged metallocene complexes of general type biph(3,4-R2C5H2)2MCl2 (biph = 1,1'-biphenyldiyl) were synthesized and characterized. For the dimethyl-substituted titanocenes and zirconocenes (R = CH3; M = Ti, Zr), preparations with increased overall yields and an optical resolution method were developed. The bis(2-tetrahydroindenyl) complexes (R,R = (CH2)4; M = Ti, Zr) were obtained by an alternative synthetic route and characterized with regard to their crystal structures. Syntheses of the phenyl-substituted derivatives (R = C6H5; M = Ti, Zr) and of a chiral, methyl-substituted vanadocene complex (R = CH3; M = V) are also reported.
Subject (DDC): 540 Chemistry
Keywords: Titanium, zirconium, vanadium, metallocene, enantioseparation
Link to License: In Copyright

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HUTTENLOCH, Monika E., Birgit DORER, Ursula RIEF, Marc-Heinrich PROSENC, Katrin SCHMIDT, Hans-Herbert BRINTZINGER, 1997. ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation. In: Journal of Organometallic Chemistry. 541(1-2), pp. 219-232. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(97)00064-8

@article{Huttenloch1997ansam-23890, title={ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation}, year={1997}, doi={10.1016/S0022-328X(97)00064-8}, number={1-2}, volume={541}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={219--232}, author={Huttenloch, Monika E. and Dorer, Birgit and Rief, Ursula and Prosenc, Marc-Heinrich and Schmidt, Katrin and Brintzinger, Hans-Herbert} }

terms-of-use 2013-07-25T08:36:18Z Brintzinger, Hans-Herbert Journal of Organometallic Chemistry ; 541 (1997), 1-2. - S. 219-232 Huttenloch, Monika E. Schmidt, Katrin Schmidt, Katrin Huttenloch, Monika E. Rief, Ursula 1997 Prosenc, Marc-Heinrich eng ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation Brintzinger, Hans-Herbert 2013-07-25T08:36:18Z Rief, Ursula Prosenc, Marc-Heinrich Dorer, Birgit Dorer, Birgit Chiral, biphenyl-bridged metallocene complexes of general type biph(3,4-R<sub>2</sub>C<sub>5</sub>H<sub>2</sub>)<sub>2</sub>MCl<sub>2</sub> (biph = 1,1'-biphenyldiyl) were synthesized and characterized. For the dimethyl-substituted titanocenes and zirconocenes (R = CH<sub>3</sub>; M = Ti, Zr), preparations with increased overall yields and an optical resolution method were developed. The bis(2-tetrahydroindenyl) complexes (R,R = (CH<sub>2</sub>)4; M = Ti, Zr) were obtained by an alternative synthetic route and characterized with regard to their crystal structures. Syntheses of the phenyl-substituted derivatives (R = C<sub>6</sub>H<sub>5</sub>; M = Ti, Zr) and of a chiral, methyl-substituted vanadocene complex (R = CH<sub>3</sub>; M = V) are also reported.

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