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Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization

Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization

Type of Publication: Journal article
URI (citable link): http://nbn-resolving.de/urn:nbn:de:bsz:352-238893
Author: Schneider, Nicole; Prosenc, Marc-Heinrich; Brintzinger, Hans-Herbert
Year of publication: 1997
Published in: Journal of Organometallic Chemistry ; 545-546 (1997). - pp. 291-295. - ISSN 0022-328X
DOI (citable link): https://dx.doi.org/10.1016/S0022-328X(97)00251-9
Summary:
Cyclopenta[l]phenanthrene titanium trichloride and its 2-methyl and phenyl derivatives were synthesized; the crystal structure of the 2-methyl-substituted complex was determined by X-ray diffraction analysis. In the presence of methylalurnoxane (MAO), these complexes give highly active catalysis for the syndiotactic polymerization of styrene; the 2-phenyl-substituted complex exceeds all previously described catalysis in its catalytic activity.
Subject (DDC): 540 Chemistry
Link to License: Terms of use

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SCHNEIDER, Nicole, Marc-Heinrich PROSENC, Hans-Herbert BRINTZINGER, 1997. Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization. In: Journal of Organometallic Chemistry. 545-546, pp. 291-295. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(97)00251-9

@article{Schneider1997Cyclo-23889, title={Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization}, year={1997}, doi={10.1016/S0022-328X(97)00251-9}, volume={545-546}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={291--295}, author={Schneider, Nicole and Prosenc, Marc-Heinrich and Brintzinger, Hans-Herbert} }

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