Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization
| Type of Publication: | Journal article |
| URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-238893 |
| Author: | Schneider, Nicole; Prosenc, Marc-Heinrich; Brintzinger, Hans-Herbert |
| Year of publication: | 1997 |
| Published in: | Journal of Organometallic Chemistry ; 545-546 (1997). - pp. 291-295. - ISSN 0022-328X |
| DOI (citable link): | https://dx.doi.org/10.1016/S0022-328X(97)00251-9 |
| Summary: |
Cyclopenta[l]phenanthrene titanium trichloride and its 2-methyl and phenyl derivatives were synthesized; the crystal structure of the 2-methyl-substituted complex was determined by X-ray diffraction analysis. In the presence of methylalurnoxane (MAO), these complexes give highly active catalysis for the syndiotactic polymerization of styrene; the 2-phenyl-substituted complex exceeds all previously described catalysis in its catalytic activity.
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| Subject (DDC): | 540 Chemistry |
| Link to License: | Terms of use |
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SCHNEIDER, Nicole, Marc-Heinrich PROSENC, Hans-Herbert BRINTZINGER, 1997. Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization. In: Journal of Organometallic Chemistry. 545-546, pp. 291-295. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(97)00251-9
@article{Schneider1997Cyclo-23889, title={Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization}, year={1997}, doi={10.1016/S0022-328X(97)00251-9}, volume={545-546}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={291--295}, author={Schneider, Nicole and Prosenc, Marc-Heinrich and Brintzinger, Hans-Herbert} }
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