Supported cyclopentadienylmetal carbonyl complexes : II. Polystyrene-supported carbonyl and nitrosyl derivatives of group VI transition metals

Gubitosa, Giuseppe; Brintzinger, Hans-Herbert

doi:10.1016/S0022-328X(00)93194-2

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Supported cyclopentadienylmetal carbonyl complexes : II. Polystyrene-supported carbonyl and nitrosyl derivatives of group VI transition metals

Publikationstyp:	Zeitschriftenartikel
URI (zitierfähiger Link):	http://nbn-resolving.de/urn:nbn:de:bsz:352-238686
Autor/innen:	Gubitosa, Giuseppe; Brintzinger, Hans-Herbert
Erscheinungsjahr:	1977
Erschienen in:	Journal of Organometallic Chemistry ; 140 (1977), 2. - S. 187-193. - ISSN 0022-328X
DOI (zitierfähiger Link):	https://dx.doi.org/10.1016/S0022-328X(00)93194-2
Zusammenfassung:	Tricarbonyl hydride derivatives of cyclopentadienyl-chromium, -molybdenum and -tungsten compounds covalently linked to a macroreticular polystyrene support are obtained by treatment of polystyrene-attached cyclopentadienyl anions with the respective metal hexacarbonyl and subsequent acidification. In contrast to the ease with which unsupported cyclopentadienyl-chromium and -molybdenum tricarbonyl hydrides lose H₂ to form dinuclear carbonyl species, no H₂ is released from their polymer-supported counterparts below about 180°C, and no dinuclear species are detectable after partial thermal decomposition at higher temperatures. The identity of the polymer-supported chromium species is confirmed by its conversion into nitrosyl derivatives.
Fachgebiet (DDC):	540 Chemie
Link zur Lizenz:	Nutzungsbedingungen

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GUBITOSA, Giuseppe, Hans-Herbert BRINTZINGER, 1977. Supported cyclopentadienylmetal carbonyl complexes : II. Polystyrene-supported carbonyl and nitrosyl derivatives of group VI transition metals. In: Journal of Organometallic Chemistry. 140(2), pp. 187-193. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)93194-2

@article{Gubitosa1977Suppo-23868, title={Supported cyclopentadienylmetal carbonyl complexes : II. Polystyrene-supported carbonyl and nitrosyl derivatives of group VI transition metals}, year={1977}, doi={10.1016/S0022-328X(00)93194-2}, number={2}, volume={140}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={187--193}, author={Gubitosa, Giuseppe and Brintzinger, Hans-Herbert} }

Gubitosa, Giuseppe terms-of-use Gubitosa, Giuseppe 2013-07-25T09:09:36Z Tricarbonyl hydride derivatives of cyclopentadienyl-chromium, -molybdenum and -tungsten compounds covalently linked to a macroreticular polystyrene support are obtained by treatment of polystyrene-attached cyclopentadienyl anions with the respective metal hexacarbonyl and subsequent acidification. In contrast to the ease with which unsupported cyclopentadienyl-chromium and -molybdenum tricarbonyl hydrides lose H<sub>2</sub> to form dinuclear carbonyl species, no H<sub>2</sub> is released from their polymer-supported counterparts below about 180°C, and no dinuclear species are detectable after partial thermal decomposition at higher temperatures. The identity of the polymer-supported chromium species is confirmed by its conversion into nitrosyl derivatives. 1977 2013-07-25T09:09:36Z Journal of Organometallic Chemistry ; 140 (1977), 2. - S. 187-193 Brintzinger, Hans-Herbert Supported cyclopentadienylmetal carbonyl complexes : II. Polystyrene-supported carbonyl and nitrosyl derivatives of group VI transition metals eng Brintzinger, Hans-Herbert