Tetrahydrothiophene tris(pentafluorophenyl)borane

Type of Publication: Journal article
URI (citable link): http://nbn-resolving.de/urn:nbn:de:bsz:352-238596
Author: Schaper, Frank; Brintzinger, Hans-Herbert
Year of publication: 2001
Published in: Acta Crystallographica Section E Structure Reports Online ; 58 (2001), 1. - pp. o77-o78. - ISSN 1600-5368. - eISSN 1600-5368
DOI (citable link): https://dx.doi.org/10.1107/S160053680102027X
Summary:
In the title compound, (C4H8S)B(C6F5)3, a comparatively long boron-sulfur distance of 2.0843 (16) Å is found, most probably due to the sterically demanding pentafluorophenylsubstituents. Bond distances and angles of the boron-aryl fragment are comparable to those found for uncoordinated MeB(C6F5)3- anions.
Subject (DDC): 540 Chemistry
Link to License: In Copyright

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SCHAPER, Frank, Hans-Herbert BRINTZINGER, 2001. Tetrahydrothiophene tris(pentafluorophenyl)borane. In: Acta Crystallographica Section E Structure Reports Online. 58(1), pp. o77-o78. ISSN 1600-5368. eISSN 1600-5368. Available under: doi: 10.1107/S160053680102027X

@article{Schaper2001Tetra-23859, title={Tetrahydrothiophene tris(pentafluorophenyl)borane}, year={2001}, doi={10.1107/S160053680102027X}, number={1}, volume={58}, issn={1600-5368}, journal={Acta Crystallographica Section E Structure Reports Online}, pages={o77--o78}, author={Schaper, Frank and Brintzinger, Hans-Herbert} }

Acta Crystallographica, Section E: Structure Reports Online ; 58 (2002), 1. - S. o77-o78 2013-07-04T07:37:39Z 2013-07-04T07:37:39Z 2001 Brintzinger, Hans-Herbert eng Schaper, Frank terms-of-use Brintzinger, Hans-Herbert In the title compound, (C<sub>4</sub>H<sub>8</sub>S)B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>, a comparatively long boron-sulfur distance of 2.0843 (16) Å is found, most probably due to the sterically demanding pentafluorophenylsubstituents. Bond distances and angles of the boron-aryl fragment are comparable to those found for uncoordinated MeB(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub><sup>-</sup> anions. Schaper, Frank Tetrahydrothiophene tris(pentafluorophenyl)borane

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