Type of Publication: | Journal article |
URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-238581 |
Author: | Hüttenhofer, Mario; Schaper, Frank; Brintzinger, Hans-Herbert |
Year of publication: | 2002 |
Published in: | Journal of Organometallic Chemistry ; 660 (2002), 1. - pp. 85-90. - ISSN 0022-328X |
DOI (citable link): | https://dx.doi.org/10.1016/S0022-328X(02)01775-8 |
Summary: |
Alkyl-substituted bis(cyclopentadienyl)dimethylsilanes react with Me2Sn(NEt2)2 and with (Me2N)4Sn to yield correspondingly substituted, meso-configurated RS-8-sila-4-stanna-s-tetrahydroindacene and axially symmetric RR,SS-4-spiro-bis(8-sila-4-stanna-s-tetrahydroindacene) compounds, respectively, which are stereoselectively converted by reaction with ZrCl4 to the corresponding meso- and rac-configurated ansa-zirconocene complexes.
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Subject (DDC): | 540 Chemistry |
Link to License: | In Copyright |
HÜTTENHOFER, Mario, Frank SCHAPER, Hans-Herbert BRINTZINGER, 2002. 8-Sila-4-stanna-s-tetrahydroindacenes as synthons for Me2Si-bridged zirconocenes : formation from biscyclopentadienyl silanes by reaction with aminostannanes. In: Journal of Organometallic Chemistry. 660(1), pp. 85-90. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(02)01775-8
@article{Huttenhofer20028Sila-23858, title={8-Sila-4-stanna-s-tetrahydroindacenes as synthons for Me2Si-bridged zirconocenes : formation from biscyclopentadienyl silanes by reaction with aminostannanes}, year={2002}, doi={10.1016/S0022-328X(02)01775-8}, number={1}, volume={660}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={85--90}, author={Hüttenhofer, Mario and Schaper, Frank and Brintzinger, Hans-Herbert} }
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