Bis(Eta3-indenyl)bis(tetrahydrofuran)magnesium(II)

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GRITZO, Holger, Frank SCHAPER, Hans-Herbert BRINTZINGER, 2004. Bis(Eta3-indenyl)bis(tetrahydrofuran)magnesium(II). In: Acta Crystallographica Section E Structure Reports Online. 60(8), pp. m1108-m1110. ISSN 1600-5368

@article{Gritzo2004Bis(E-23845, title={Bis(Eta3-indenyl)bis(tetrahydrofuran)magnesium(II)}, year={2004}, doi={10.1107/S1600536804016149}, number={8}, volume={60}, issn={1600-5368}, journal={Acta Crystallographica Section E Structure Reports Online}, pages={m1108--m1110}, author={Gritzo, Holger and Schaper, Frank and Brintzinger, Hans-Herbert} }

Schaper, Frank Gritzo, Holger deposit-license Brintzinger, Hans-Herbert eng In the crystal structure of the title compound, [Mg(C<sub>4</sub>H<sub>8</sub>O)<sub>2</sub>(C<sub>9</sub>H<sub>7</sub>)<sub>2</sub>], the two indenyl ligands are bound to the Mg atom in a manner intermediate between Eta<sup>1</sup>- and Eta<sup>3</sup>-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)<sub>2</sub> adduct (THF is tetrahydrofuran). A crystallographic C<sub>2</sub> axis bisects the O-Mg-O angle. Brintzinger, Hans-Herbert Acta Crystallographica Section E: Structure Reports Online ; 60 (2004), 8. - m1108-m1110 2013-07-24T19:14:07Z Bis(Eta<sup>3</sup>-indenyl)bis(tetrahydrofuran)magnesium(II) 2004 Gritzo, Holger Schaper, Frank 2013-07-24T19:14:07Z

Dateiabrufe seit 01.10.2014 (Informationen über die Zugriffsstatistik)

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