Über Dipyridyl-Metallkomplexe III. Austausch und Racemisierung : Metallionen und biologische Wirkung, 33. Mitteilung
| Type of Publication: | Journal article |
| URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-238226 |
| Author: | Brintzinger, Hans-Herbert; Fallab, Silvio; Erlenmeyer, Hans |
| Year of publication: | 1955 |
| Published in: | Helvetica Chimica Acta ; 38 (1955), 3. - pp. 557-559. - ISSN 0018-019X. - eISSN 1522-2675 |
| DOI (citable link): | https://dx.doi.org/10.1002/hlca.19550380302 |
| Summary in another language: |
In exchange reaction studies of the [Fe(Dipy)3]2+ complex it was found that the rate of racemization is greater than the rate of dissoziation. This fact suggests racemization through intramolecular rearrangement. Such a reaction can be regarded as a model for an enzymesubstrate-reaction taking place in the coordination-sphere of a metallion.
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| Subject (DDC): | 540 Chemistry |
| Link to License: | Terms of use |
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BRINTZINGER, Hans-Herbert, Silvio FALLAB, Hans ERLENMEYER, 1955. Über Dipyridyl-Metallkomplexe III. Austausch und Racemisierung : Metallionen und biologische Wirkung, 33. Mitteilung. In: Helvetica Chimica Acta. 38(3), pp. 557-559. ISSN 0018-019X. eISSN 1522-2675. Available under: doi: 10.1002/hlca.19550380302
@article{Brintzinger1955Dipyr-23822, title={Über Dipyridyl-Metallkomplexe III. Austausch und Racemisierung : Metallionen und biologische Wirkung, 33. Mitteilung}, year={1955}, doi={10.1002/hlca.19550380302}, number={3}, volume={38}, issn={0018-019X}, journal={Helvetica Chimica Acta}, pages={557--559}, author={Brintzinger, Hans-Herbert and Fallab, Silvio and Erlenmeyer, Hans} }
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